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\u7efc\u4e0a\u6240\u8ff0\uff0c\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u5728\u7eff\u8272\u5316\u5b66\u4e2d\u7684\u5e94\u7528\u4e0d\u4ec5\u4f53\u73b0\u4e86\u5176\u5353\u8d8a\u7684\u50ac\u5316\u6027\u80fd\u548c\u73af\u4fdd\u4f18\u52bf\uff0c\u66f4\u4e3a\u5316\u5b66\u5de5\u4e1a\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u63d0\u4f9b\u4e86\u5f3a\u6709\u529b\u7684\u652f\u6301\u3002\u901a\u8fc7\u4e0d\u65ad\u63a2\u7d22\u548c\u4f18\u5316\u5176\u5e94\u7528\u65b9\u5f0f\uff0c\u6211\u4eec\u53ef\u4ee5\u671f\u5f85TMEDA\u5728\u672a\u6765\u5316\u5b66\u53d1\u5c55\u4e2d\u626e\u6f14\u66f4\u52a0\u91cd\u8981\u7684\u89d2\u8272\u3002<\/p>\n

\u5b9e\u4f8b\u89e3\u6790\uff1a\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u5728\u7eff\u8272\u5316\u5b66\u4e2d\u7684\u6210\u529f\u5e94\u7528<\/h3>\n

\u4e3a\u4e86\u66f4\u597d\u5730\u7406\u89e3\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\uff08TMEDA\uff09\u5728\u7eff\u8272\u5316\u5b66\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\uff0c\u6211\u4eec\u53ef\u4ee5\u901a\u8fc7\u51e0\u4e2a\u5177\u4f53\u7684\u6848\u4f8b\u8fdb\u884c\u6df1\u5165\u63a2\u8ba8\u3002\u8fd9\u4e9b\u6848\u4f8b\u5c55\u793a\u4e86TMEDA\u5982\u4f55\u5728\u4e0d\u540c\u7684\u5316\u5b66\u53cd\u5e94\u4e2d\u53d1\u6325\u4f5c\u7528\uff0c\u4ee5\u53ca\u5b83\u6240\u5e26\u6765\u7684\u73af\u5883\u548c\u7ecf\u6d4e\u53cc\u91cd\u6548\u76ca\u3002<\/p>\n

\u6848\u4f8b\u4e00\uff1a\u836f\u7269\u5408\u6210\u4e2d\u7684\u9ad8\u6548\u50ac\u5316<\/h4>\n

\u5728\u73b0\u4ee3\u836f\u7269\u5408\u6210\u4e2d\uff0cTMEDA\u88ab\u5e7f\u6cdb\u7528\u4e8e\u94af\u50ac\u5316\u7684Heck\u53cd\u5e94\u3002\u8fd9\u79cd\u53cd\u5e94\u662f\u5236\u5907\u590d\u6742\u6709\u673a\u5206\u5b50\u7684\u91cd\u8981\u5de5\u5177\uff0c\u5c24\u5176\u5728\u6297\u764c\u836f\u7269\u548c\u6297\u75c5\u6bd2\u836f\u7269\u7684\u5408\u6210\u4e2d\u4e0d\u53ef\u6216\u7f3a\u3002\u901a\u8fc7\u4e0e\u94af\u50ac\u5316\u5242\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u5408\u7269\uff0cTMEDA\u663e\u8457\u63d0\u9ad8\u4e86\u53cd\u5e94\u7684\u9009\u62e9\u6027\u548c\u4ea7\u7387\u3002\u4f8b\u5982\uff0c\u5728\u67d0\u6297\u764c\u836f\u7269\u4e2d\u95f4\u4f53\u7684\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u4f7f\u7528TMEDA\u4f5c\u4e3a\u52a9\u50ac\u5316\u5242\uff0c\u4e0d\u4ec5\u5c06\u53cd\u5e94\u65f6\u95f4\u7f29\u77ed\u4e86\u4e00\u534a\uff0c\u8fd8\u5c06\u526f\u4ea7\u7269\u7684\u751f\u6210\u91cf\u51cf\u5c11\u4e86\u8fd170%\u3002\u8fd9\u4e0d\u4ec5\u964d\u4f4e\u4e86\u751f\u4ea7\u6210\u672c\uff0c\u8fd8\u51cf\u5c11\u4e86\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u3002<\/p>\n\n\n\n\n\n
\u53cd\u5e94\u7c7b\u578b<\/th>\n\u4f7f\u7528\u50ac\u5316\u5242<\/th>\n\u4ea7\u7387\u63d0\u5347<\/th>\n\u526f\u4ea7\u7269\u51cf\u5c11<\/th>\n<\/tr>\n<\/thead>\n
Heck\u53cd\u5e94<\/td>\nTMEDA<\/td>\n+30%<\/td>\n-70%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u6848\u4f8b\u4e8c\uff1a\u6750\u6599\u79d1\u5b66\u4e2d\u7684\u73af\u4fdd\u9009\u62e9<\/h4>\n

\u5728\u805a\u5408\u7269\u6750\u6599\u7684\u5408\u6210\u4e2d\uff0cTMEDA\u540c\u6837\u5c55\u73b0\u51fa\u4e86\u5176\u72ec\u7279\u7684\u4ef7\u503c\u3002\u4ee5\u805a\u6c28\u916f\u7684\u5408\u6210\u4e3a\u4f8b\uff0c\u4f20\u7edf\u7684\u50ac\u5316\u5242\u5f80\u5f80\u542b\u6709\u91cd\u91d1\u5c5e\uff0c\u53ef\u80fd\u5bfc\u81f4\u73af\u5883\u6c61\u67d3\u3002\u800c\u91c7\u7528TMEDA\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5219\u80fd\u6709\u6548\u907f\u514d\u8fd9\u4e00\u95ee\u9898\u3002\u901a\u8fc7\u4e0e\u5f02\u6c30\u9178\u916f\u53cd\u5e94\uff0cTMEDA\u4e0d\u4ec5\u63d0\u9ad8\u4e86\u805a\u5408\u53cd\u5e94\u7684\u6548\u7387\uff0c\u8fd8\u786e\u4fdd\u4e86\u7ec8\u4ea7\u54c1\u7684\u73af\u4fdd\u6027\u80fd\u3002\u67d0\u7814\u7a76\u663e\u793a\uff0c\u4f7f\u7528TMEDA\u5408\u6210\u7684\u805a\u6c28\u916f\u6ce1\u6cab\u6750\u6599\uff0c\u5176\u673a\u68b0\u6027\u80fd\u548c\u8010\u4e45\u6027\u5747\u4f18\u4e8e\u4f20\u7edf\u65b9\u6cd5\u5236\u5f97\u7684\u4ea7\u54c1\uff0c\u540c\u65f6\u751f\u4ea7\u8fc7\u7a0b\u4e2d\u7684\u6c61\u67d3\u7269\u6392\u653e\u51cf\u5c11\u4e86\u7ea650%\u3002<\/p>\n\n\n\n\n\n
\u6750\u6599\u7c7b\u578b<\/th>\n\u4f7f\u7528\u50ac\u5316\u5242<\/th>\n\u6027\u80fd\u63d0\u5347<\/th>\n\u6c61\u67d3\u7269\u51cf\u5c11<\/th>\n<\/tr>\n<\/thead>\n
\u805a\u6c28\u916f<\/td>\nTMEDA<\/td>\n+20%<\/td>\n-50%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u6848\u4f8b\u4e09\uff1a\u73af\u5883\u6cbb\u7406\u4e2d\u7684\u521b\u65b0\u5e94\u7528<\/h4>\n

\u5728\u6c34\u5904\u7406\u9886\u57df\uff0cTMEDA\u4e5f\u88ab\u7528\u4f5c\u50ac\u5316\u5242\u6765\u52a0\u901f\u67d0\u4e9b\u6709\u5bb3\u7269\u8d28\u7684\u5206\u89e3\u3002\u4f8b\u5982\uff0c\u5728\u5904\u7406\u542b\u915a\u5e9f\u6c34\u7684\u8fc7\u7a0b\u4e2d\uff0cTMEDA\u4e0e\u94c1\u79bb\u5b50\u5f62\u6210\u7684\u914d\u5408\u7269\u80fd\u591f\u6709\u6548\u50ac\u5316\u915a\u7684\u6c27\u5316\u53cd\u5e94\uff0c\u5c06\u5176\u8f6c\u5316\u4e3a\u65e0\u5bb3\u7684\u5c0f\u5206\u5b50\u5316\u5408\u7269\u3002\u8fd9\u79cd\u65b9\u6cd5\u4e0d\u4ec5\u901f\u5ea6\u5feb\uff0c\u800c\u4e14\u6548\u7387\u9ad8\uff0c\u9002\u5408\u5927\u89c4\u6a21\u5de5\u4e1a\u5e94\u7528\u3002\u5b9e\u9a8c\u6570\u636e\u8868\u660e\uff0c\u4f7f\u7528TMEDA\u50ac\u5316\u5242\u7684\u5904\u7406\u7cfb\u7edf\uff0c\u80fd\u591f\u5c06\u915a\u7684\u53bb\u9664\u7387\u63d0\u9ad8\u523095%\u4ee5\u4e0a\uff0c\u8fdc\u9ad8\u4e8e\u4f20\u7edf\u65b9\u6cd5\u3002<\/p>\n\n\n\n\n\n
\u5904\u7406\u5bf9\u8c61<\/th>\n\u4f7f\u7528\u50ac\u5316\u5242<\/th>\n\u53bb\u9664\u7387\u63d0\u5347<\/th>\n\u80fd\u8017\u964d\u4f4e<\/th>\n<\/tr>\n<\/thead>\n
\u542b\u915a\u5e9f\u6c34<\/td>\nTMEDA<\/td>\n+40%<\/td>\n-30%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u901a\u8fc7\u8fd9\u4e9b\u5177\u4f53\u6848\u4f8b\uff0c\u6211\u4eec\u53ef\u4ee5\u6e05\u695a\u5730\u770b\u5230\uff0c\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u5728\u7eff\u8272\u5316\u5b66\u4e2d\u7684\u5e94\u7528\u4e0d\u4ec5\u5b9e\u73b0\u4e86\u6280\u672f\u4e0a\u7684\u7a81\u7834\uff0c\u4e5f\u5e26\u6765\u4e86\u663e\u8457\u7684\u73af\u5883\u548c\u793e\u4f1a\u6548\u76ca\u3002\u8fd9\u4e9b\u6210\u529f\u7684\u5e94\u7528\u5b9e\u4f8b\u4e3a\u672a\u6765\u7684\u5316\u5b66\u6280\u672f\u521b\u65b0\u63d0\u4f9b\u4e86\u5b9d\u8d35\u7684\u53c2\u8003\u548c\u542f\u793a\u3002<\/p>\n

\u7eff\u8272\u5316\u5b66\u4e2d\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u4e0e\u5176\u4ed6\u50ac\u5316\u5242\u7684\u5bf9\u6bd4\u5206\u6790<\/h3>\n

\u5728\u7eff\u8272\u5316\u5b66\u9886\u57df\uff0c\u50ac\u5316\u5242\u7684\u9009\u62e9\u81f3\u5173\u91cd\u8981\uff0c\u56e0\u4e3a\u5b83\u76f4\u63a5\u5f71\u54cd\u53cd\u5e94\u7684\u6548\u7387\u3001\u9009\u62e9\u6027\u548c\u73af\u5883\u5f71\u54cd\u3002\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\uff08TMEDA\uff09\u4f5c\u4e3a\u4e00\u79cd\u65b0\u5174\u7684\u50ac\u5316\u5242\uff0c\u4e0e\u4f20\u7edf\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u5177\u6709\u72ec\u7279\u7684\u4f18\u52bf\u548c\u5c40\u9650\u6027\u3002\u4ee5\u4e0b\u5c06\u4ece\u53cd\u5e94\u6548\u7387\u3001\u73af\u5883\u53cb\u597d\u6027\u548c\u6210\u672c\u6548\u76ca\u4e09\u4e2a\u65b9\u9762\uff0c\u8be6\u7ec6\u6bd4\u8f83TMEDA\u4e0e\u5176\u4ed6\u5e38\u89c1\u50ac\u5316\u5242\u7684\u5dee\u5f02\u3002<\/p>\n

\u53cd\u5e94\u6548\u7387<\/h4>\n

\u5728\u53cd\u5e94\u6548\u7387\u65b9\u9762\uff0cTMEDA\u4ee5\u5176\u5353\u8d8a\u7684\u8868\u73b0\u8131\u9896\u800c\u51fa\u3002\u5b83\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u67d0\u4e9b\u7279\u5b9a\u53cd\u5e94\u7684\u901f\u5ea6\u548c\u4ea7\u7387\uff0c\u5c24\u5176\u662f\u90a3\u4e9b\u6d89\u53ca\u91d1\u5c5e\u50ac\u5316\u7684\u53cd\u5e94\u3002\u4f8b\u5982\uff0c\u5728\u94af\u50ac\u5316\u7684Suzuki-Miyaura\u5076\u8054\u53cd\u5e94\u4e2d\uff0cTMEDA\u901a\u8fc7\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u5408\u7269\uff0c\u5927\u5e45\u63d0\u5347\u4e86\u53cd\u5e94\u7684\u9009\u62e9\u6027\u548c\u4ea7\u7387\u3002\u7136\u800c\uff0c\u4f20\u7edf\u7684\u5747\u76f8\u50ac\u5316\u5242\u5982\u6c2f\u5316\u94af\uff08PdCl2\uff09\u867d\u7136\u5728\u4e00\u4e9b\u53cd\u5e94\u4e2d\u4e5f\u80fd\u8fbe\u5230\u8f83\u9ad8\u7684\u6548\u7387\uff0c\u4f46\u901a\u5e38\u9700\u8981\u66f4\u9ad8\u7684\u6e29\u5ea6\u548c\u538b\u529b\u6761\u4ef6\uff0c\u8fd9\u589e\u52a0\u4e86\u80fd\u8017\u548c\u64cd\u4f5c\u96be\u5ea6\u3002<\/p>\n\n\n\n\n\n\n
\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n\u53cd\u5e94\u6548\u7387\u63d0\u5347<\/th>\n\u64cd\u4f5c\u6761\u4ef6\u8981\u6c42<\/th>\n<\/tr>\n<\/thead>\n
TMEDA<\/td>\n\u9ad8<\/td>\n\u4e2d\u7b49<\/td>\n<\/tr>\n
PdCl2<\/td>\n\u4e2d<\/td>\n\u9ad8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u73af\u5883\u53cb\u597d\u6027<\/h4>\n

\u4ece\u73af\u5883\u53cb\u597d\u6027\u7684\u89d2\u5ea6\u6765\u770b\uff0cTMEDA\u660e\u663e\u4f18\u4e8e\u8bb8\u591a\u4f20\u7edf\u50ac\u5316\u5242\u3002\u5b83\u662f\u4e00\u79cd\u6709\u673a\u5316\u5408\u7269\uff0c\u6bd2\u6027\u8f83\u4f4e\u4e14\u6613\u4e8e\u751f\u7269\u964d\u89e3\uff0c\u8fd9\u5bf9\u51cf\u5c11\u5316\u5b66\u5de5\u4e1a\u7684\u73af\u5883\u8d1f\u62c5\u81f3\u5173\u91cd\u8981\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u4e00\u4e9b\u4f20\u7edf\u50ac\u5316\u5242\u5982\u516d\u6c1f\u78f7\u9178\u94af\uff08Pd(PPh3)4\uff09\u867d\u7136\u5728\u67d0\u4e9b\u53cd\u5e94\u4e2d\u975e\u5e38\u6709\u6548\uff0c\u4f46\u7531\u4e8e\u5176\u590d\u6742\u7684\u7ed3\u6784\u548c\u9ad8\u6bd2\u6027\uff0c\u5904\u7406\u548c\u5e9f\u5f03\u65f6\u53ef\u80fd\u4f1a\u5bf9\u73af\u5883\u9020\u6210\u4e25\u91cd\u6c61\u67d3\u3002<\/p>\n\n\n\n\n\n\n
\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n\u6bd2\u6027\u7b49\u7ea7<\/th>\n\u751f\u7269\u964d\u89e3\u6027<\/th>\n<\/tr>\n<\/thead>\n
TMEDA<\/td>\n\u4f4e<\/td>\n\u9ad8<\/td>\n<\/tr>\n
Pd(PPh3)4<\/td>\n\u9ad8<\/td>\n\u4f4e<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u6210\u672c\u6548\u76ca<\/h4>\n

\u81f3\u4e8e\u6210\u672c\u6548\u76ca\uff0cTMEDA\u4e5f\u6709\u5176\u72ec\u7279\u7684\u4f18\u52bf\u3002\u5c3d\u7ba1\u5176\u521d\u59cb\u6210\u672c\u53ef\u80fd\u7565\u9ad8\u4e8e\u67d0\u4e9b\u4f20\u7edf\u50ac\u5316\u5242\uff0c\u4f46\u7531\u4e8e\u5176\u9ad8\u6548\u7387\u548c\u4f4e\u80fd\u8017\uff0c\u957f\u671f\u6765\u770b\uff0c\u4f7f\u7528TMEDA\u53ef\u4ee5\u663e\u8457\u964d\u4f4e\u6574\u4f53\u751f\u4ea7\u6210\u672c\u3002\u6b64\u5916\uff0cTMEDA\u7684\u53ef\u56de\u6536\u6027\u548c\u91cd\u590d\u5229\u7528\u6027\u4e5f\u4e3a\u5176\u5728\u5de5\u4e1a\u89c4\u6a21\u4e0a\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u7ecf\u6d4e\u4e0a\u7684\u53ef\u884c\u6027\u3002<\/p>\n\n\n\n\n\n\n
\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n\u521d\u59cb\u6210\u672c<\/th>\n\u957f\u671f\u6210\u672c\u8282\u7701<\/th>\n<\/tr>\n<\/thead>\n
TMEDA<\/td>\n\u4e2d<\/td>\n\u9ad8<\/td>\n<\/tr>\n
PdCl2<\/td>\n\u4f4e<\/td>\n\u4e2d<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

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\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/44879<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/43941<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/165<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/cas-1704-62-7\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/873<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/22.jpg<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/wp-content\/uploads\/2021\/05\/1-2.jpg<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/dabco-pt303-tertiary-amine-catalyst-dabco-pt303-catalyst-dabco-pt303\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/sponge-foaming-catalyst-smp\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/36.jpg<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"

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