{"id":6249,"date":"2025-02-15T16:06:16","date_gmt":"2025-02-15T08:06:16","guid":{"rendered":"https:\/\/www.xindianchem.com\/6249.html"},"modified":"2025-02-15T16:06:16","modified_gmt":"2025-02-15T08:06:16","slug":"%e8%81%9a%e6%b0%a8%e9%85%af%e5%82%ac%e5%8c%96%e5%89%829727%e5%9c%a8%e4%b8%8d%e5%90%8c%e6%b8%a9%e5%ba%a6%e6%9d%a1%e4%bb%b6%e4%b8%8b%e7%9a%84%e7%a8%b3%e5%ae%9a%e6%80%a7%e6%b5%8b%e8%af%95","status":"publish","type":"post","link":"https:\/\/www.xindianchem.com\/6249.html","title":{"rendered":"\u805a\u6c28\u916f\u50ac\u5316\u52429727\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5"},"content":{"rendered":"<h3>\u5f15\u8a00<\/h3>\n<p>\u805a\u6c28\u916f\uff08Polyurethane, PU\uff09\u662f\u4e00\u79cd\u7531\u5f02\u6c30\u9178\u916f\u548c\u591a\u5143\u9187\u53cd\u5e94\u751f\u6210\u7684\u9ad8\u5206\u5b50\u6750\u6599\uff0c\u56e0\u5176\u4f18\u5f02\u7684\u7269\u7406\u6027\u80fd\u548c\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u5728\u4f17\u591a\u9886\u57df\u5f97\u5230\u4e86\u5e7f\u6cdb\u5e94\u7528\u3002\u4ece\u5efa\u7b51\u4fdd\u6e29\u3001\u6c7d\u8f66\u5236\u9020\u5230\u5bb6\u5177\u3001\u978b\u6750\u7b49\uff0c\u805a\u6c28\u916f\u7684\u8eab\u5f71\u65e0\u5904\u4e0d\u5728\u3002\u7136\u800c\uff0c\u805a\u6c28\u916f\u7684\u5408\u6210\u8fc7\u7a0b\u590d\u6742\uff0c\u5c24\u5176\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\uff0c\u50ac\u5316\u5242\u7684\u9009\u62e9\u81f3\u5173\u91cd\u8981\u3002\u50ac\u5316\u5242\u4e0d\u4ec5\u5f71\u54cd\u53cd\u5e94\u901f\u7387\uff0c\u8fd8\u51b3\u5b9a\u4e86\u7ec8\u4ea7\u54c1\u7684\u6027\u80fd\u548c\u8d28\u91cf\u3002\u56e0\u6b64\uff0c\u5bf9\u805a\u6c28\u916f\u50ac\u5316\u5242\u7684\u7814\u7a76\u4e00\u76f4\u662f\u5b66\u672f\u754c\u548c\u5de5\u4e1a\u754c\u7684\u70ed\u70b9\u3002<\/p>\n<p>9727\u4f5c\u4e3a\u4e00\u79cd\u9ad8\u6548\u7684\u805a\u6c28\u916f\u50ac\u5316\u5242\uff0c\u8fd1\u5e74\u6765\u5907\u53d7\u5173\u6ce8\u3002\u5b83\u5c5e\u4e8e\u53d4\u80fa\u7c7b\u50ac\u5316\u5242\uff0c\u5177\u6709\u826f\u597d\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u80fd\u591f\u6709\u6548\u4fc3\u8fdb\u5f02\u6c30\u9178\u916f\u4e0e\u591a\u5143\u9187\u4e4b\u95f4\u7684\u53cd\u5e94\u30029727\u50ac\u5316\u5242\u7684\u72ec\u7279\u4e4b\u5904\u5728\u4e8e\u5176\u80fd\u591f\u5728\u8f83\u5bbd\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u4fdd\u6301\u8f83\u9ad8\u7684\u50ac\u5316\u6548\u7387\uff0c\u540c\u65f6\u5bf9\u73af\u5883\u53cb\u597d\uff0c\u7b26\u5408\u73b0\u4ee3\u5316\u5de5\u751f\u4ea7\u5bf9\u7eff\u8272\u5316\u5b66\u7684\u8981\u6c42\u3002\u672c\u6587\u5c06\u91cd\u70b9\u63a2\u8ba89727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff0c\u65e8\u5728\u4e3a\u805a\u6c28\u916f\u884c\u4e1a\u7684\u5e94\u7528\u63d0\u4f9b\u79d1\u5b66\u4f9d\u636e\u548c\u6280\u672f\u652f\u6301\u3002<\/p>\n<p>\u901a\u8fc7\u5bf99727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u8fdb\u884c\u7cfb\u7edf\u7814\u7a76\uff0c\u53ef\u4ee5\u6df1\u5165\u4e86\u89e3\u5176\u5728\u5b9e\u9645\u751f\u4ea7\u4e2d\u7684\u8868\u73b0\uff0c\u4f18\u5316\u751f\u4ea7\u5de5\u827a\uff0c\u63d0\u9ad8\u4ea7\u54c1\u8d28\u91cf\u3002\u6b64\u5916\uff0c\u672c\u6587\u8fd8\u5c06\u7ed3\u5408\u56fd\u5185\u5916\u76f8\u5173\u6587\u732e\uff0c\u5206\u67909772\u50ac\u5316\u5242\u7684\u6027\u80fd\u7279\u70b9\uff0c\u5e76\u5bf9\u5176\u672a\u6765\u53d1\u5c55\u65b9\u5411\u63d0\u51fa\u5c55\u671b\u3002\u5e0c\u671b\u672c\u6587\u7684\u7814\u7a76\u6210\u679c\u80fd\u591f\u4e3a\u805a\u6c28\u916f\u884c\u4e1a\u7684\u53d1\u5c55\u63d0\u4f9b\u6709\u76ca\u7684\u53c2\u8003\u3002<\/p>\n<h3>9727\u50ac\u5316\u5242\u7684\u5316\u5b66\u7ed3\u6784\u4e0e\u7269\u7406\u6027\u8d28<\/h3>\n<p>9727\u50ac\u5316\u5242\u662f\u4e00\u79cd\u5178\u578b\u7684\u53d4\u80fa\u7c7b\u5316\u5408\u7269\uff0c\u5316\u5b66\u540d\u79f0\u4e3aN,N-\u4e8c\u7532\u57fa\u73af\u5df1\u80fa\uff08DMCHA\uff09\u3002\u5176\u5206\u5b50\u5f0f\u4e3aC8H17N\uff0c\u5206\u5b50\u91cf\u4e3a127.23 g\/mol\u3002\u8be5\u50ac\u5316\u5242\u7684\u5316\u5b66\u7ed3\u6784\u5982\u88681\u6240\u793a\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5316\u5b66\u540d\u79f0<\/th>\n<th>N,N-\u4e8c\u7532\u57fa\u73af\u5df1\u80fa (DMCHA)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C8H17N<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>127.23 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>CAS\u53f7<\/td>\n<td>101-84-6<\/td>\n<\/tr>\n<tr>\n<td>\u5bc6\u5ea6<\/td>\n<td>0.85 g\/cm\u00b3 (20\u00b0C)<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>-15\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>165\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u95ea\u70b9<\/td>\n<td>55\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u6613\u6eb6\u4e8e\u6c34\u3001\u3001\u7b49\u6709\u673a\u6eb6\u5242<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>9727\u50ac\u5316\u5242\u7684\u7269\u7406\u6027\u8d28\u4f7f\u5176\u5728\u805a\u6c28\u916f\u5408\u6210\u8fc7\u7a0b\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6eb6\u89e3\u6027\u548c\u5206\u6563\u6027\u3002\u5b83\u80fd\u591f\u8fc5\u901f\u6eb6\u89e3\u5728\u591a\u5143\u9187\u548c\u5f02\u6c30\u9178\u916f\u4e2d\uff0c\u5f62\u6210\u5747\u5300\u7684\u53cd\u5e94\u4f53\u7cfb\uff0c\u4ece\u800c\u6709\u6548\u5730\u4fc3\u8fdb\u53cd\u5e94\u7684\u8fdb\u884c\u3002\u6b64\u5916\uff0c9727\u50ac\u5316\u5242\u7684\u4f4e\u7194\u70b9\u548c\u9002\u4e2d\u7684\u6cb8\u70b9\u4f7f\u5f97\u5b83\u5728\u5e38\u6e29\u4e0b\u4e3a\u6db2\u6001\uff0c\u4fbf\u4e8e\u64cd\u4f5c\u548c\u50a8\u5b58\uff0c\u51cf\u5c11\u4e86\u751f\u4ea7\u548c\u8fd0\u8f93\u8fc7\u7a0b\u4e2d\u7684\u96be\u5ea6\u3002<\/p>\n<h4>9727\u50ac\u5316\u5242\u7684\u50ac\u5316\u673a\u7406<\/h4>\n<p>9727\u50ac\u5316\u5242\u4f5c\u4e3a\u53d4\u80fa\u7c7b\u5316\u5408\u7269\uff0c\u5176\u50ac\u5316\u673a\u7406\u4e3b\u8981\u901a\u8fc7\u4ee5\u4e0b\u4e24\u79cd\u9014\u5f84\u5b9e\u73b0\uff1a<\/p>\n<ol>\n<li>\n<p><strong>\u52a0\u901f\u5f02\u6c30\u9178\u916f\u4e0e\u591a\u5143\u9187\u7684\u53cd\u5e94<\/strong>\uff1a\u53d4\u80fa\u7c7b\u50ac\u5316\u5242\u80fd\u591f\u4e0e\u5f02\u6c30\u9178\u916f\u4e2d\u7684-N=C=O\u57fa\u56e2\u53d1\u751f\u5f31\u914d\u4f4d\u4f5c\u7528\uff0c\u964d\u4f4e\u5176\u53cd\u5e94\u6d3b\u5316\u80fd\uff0c\u4ece\u800c\u52a0\u901f\u5f02\u6c30\u9178\u916f\u4e0e\u591a\u5143\u9187\u4e4b\u95f4\u7684\u52a0\u6210\u53cd\u5e94\u3002\u5177\u4f53\u6765\u8bf4\uff0c\u53d4\u80fa\u4e2d\u7684\u6c2e\u539f\u5b50\u5e26\u6709\u5b64\u5bf9\u7535\u5b50\uff0c\u80fd\u591f\u4e0e\u5f02\u6c30\u9178\u916f\u4e2d\u7684\u78b3\u539f\u5b50\u5f62\u6210\u6c22\u952e\u6216\u914d\u4f4d\u952e\uff0c\u524a\u5f31\u78b3-\u6c2e\u53cc\u952e\u7684\u5f3a\u5ea6\uff0c\u4f7f\u53cd\u5e94\u66f4\u5bb9\u6613\u8fdb\u884c\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u8c03\u8282\u53cd\u5e94\u901f\u7387\u548c\u9009\u62e9\u6027<\/strong>\uff1a9727\u50ac\u5316\u5242\u4e0d\u4ec5\u80fd\u591f\u52a0\u901f\u53cd\u5e94\uff0c\u8fd8\u80fd\u901a\u8fc7\u8c03\u8282\u53cd\u5e94\u901f\u7387\u548c\u9009\u62e9\u6027\u6765\u63a7\u5236\u7ec8\u4ea7\u54c1\u7684\u6027\u80fd\u3002\u4f8b\u5982\uff0c\u5728\u8f6f\u6ce1\u805a\u6c28\u916f\u7684\u5408\u6210\u4e2d\uff0c9727\u50ac\u5316\u5242\u53ef\u4ee5\u4f18\u5148\u4fc3\u8fdb\u53d1\u6ce1\u53cd\u5e94\uff0c\u51cf\u5c11\u526f\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u4ece\u800c\u83b7\u5f97\u7406\u60f3\u7684\u6ce1\u6cab\u7ed3\u6784\u548c\u7269\u7406\u6027\u80fd\u3002\u800c\u5728\u786c\u6ce1\u805a\u6c28\u916f\u7684\u5408\u6210\u4e2d\uff0c9727\u50ac\u5316\u5242\u5219\u53ef\u4ee5\u8c03\u8282\u4ea4\u8054\u5bc6\u5ea6\uff0c\u6539\u5584\u6750\u6599\u7684\u673a\u68b0\u5f3a\u5ea6\u548c\u8010\u70ed\u6027\u3002<\/p>\n<\/li>\n<\/ol>\n<h4>9727\u50ac\u5316\u5242\u7684\u5e94\u7528\u8303\u56f4<\/h4>\n<p>9727\u50ac\u5316\u5242\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5404\u7c7b\u805a\u6c28\u916f\u4ea7\u54c1\u7684\u751f\u4ea7\u4e2d\uff0c\u7279\u522b\u662f\u5728\u4ee5\u4e0b\u51e0\u4e2a\u9886\u57df\u8868\u73b0\u51fa\u8272\uff1a<\/p>\n<ol>\n<li>\n<p><strong>\u8f6f\u6ce1\u805a\u6c28\u916f<\/strong>\uff1a9727\u50ac\u5316\u5242\u80fd\u591f\u6709\u6548\u4fc3\u8fdb\u53d1\u6ce1\u53cd\u5e94\uff0c\u9002\u7528\u4e8e\u5e8a\u57ab\u3001\u6c99\u53d1\u3001\u6c7d\u8f66\u5ea7\u6905\u7b49\u8f6f\u6ce1\u5236\u54c1\u7684\u751f\u4ea7\u3002\u5b83\u80fd\u591f\u63d0\u9ad8\u6ce1\u6cab\u7684\u7a33\u5b9a\u6027\u548c\u5f39\u6027\uff0c\u5ef6\u957f\u4ea7\u54c1\u7684\u4f7f\u7528\u5bff\u547d\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u786c\u6ce1\u805a\u6c28\u916f<\/strong>\uff1a\u5728\u5efa\u7b51\u4fdd\u6e29\u3001\u51b7\u85cf\u8bbe\u5907\u7b49\u9886\u57df\uff0c9727\u50ac\u5316\u5242\u88ab\u7528\u4e8e\u5236\u5907\u786c\u6ce1\u805a\u6c28\u916f\u3002\u5b83\u53ef\u4ee5\u8c03\u8282\u4ea4\u8054\u5bc6\u5ea6\uff0c\u589e\u5f3a\u6750\u6599\u7684\u673a\u68b0\u5f3a\u5ea6\u548c\u9694\u70ed\u6027\u80fd\uff0c\u6ee1\u8db3\u4e0d\u540c\u5e94\u7528\u573a\u666f\u7684\u9700\u6c42\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u6d82\u6599\u4e0e\u80f6\u9ecf\u5242<\/strong>\uff1a9727\u50ac\u5316\u5242\u8fd8\u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u6c28\u916f\u6d82\u6599\u548c\u80f6\u9ecf\u5242\u7684\u751f\u4ea7\u4e2d\u3002\u5b83\u80fd\u591f\u52a0\u901f\u56fa\u5316\u53cd\u5e94\uff0c\u7f29\u77ed\u65bd\u5de5\u65f6\u95f4\uff0c\u63d0\u9ad8\u6d82\u5c42\u7684\u9644\u7740\u529b\u548c\u8010\u78e8\u6027\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u5f39\u6027\u4f53<\/strong>\uff1a\u5728\u805a\u6c28\u916f\u5f39\u6027\u4f53\u7684\u751f\u4ea7\u4e2d\uff0c9727\u50ac\u5316\u5242\u80fd\u591f\u4fc3\u8fdb\u4ea4\u8054\u53cd\u5e94\uff0c\u8d4b\u4e88\u6750\u6599\u4f18\u5f02\u7684\u5f39\u6027\u548c\u8010\u4e45\u6027\uff0c\u9002\u7528\u4e8e\u8fd0\u52a8\u978b\u5e95\u3001\u4f20\u9001\u5e26\u7b49\u4ea7\u54c1\u7684\u5236\u9020\u3002<\/p>\n<\/li>\n<\/ol>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c9727\u50ac\u5316\u5242\u51ed\u501f\u5176\u72ec\u7279\u7684\u5316\u5b66\u7ed3\u6784\u548c\u7269\u7406\u6027\u8d28\uff0c\u5728\u805a\u6c28\u916f\u5408\u6210\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u548c\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u63a5\u4e0b\u6765\uff0c\u6211\u4eec\u5c06\u91cd\u70b9\u63a2\u8ba89727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff0c\u4ee5\u8fdb\u4e00\u6b65\u63ed\u793a\u5176\u5728\u5b9e\u9645\u751f\u4ea7\u4e2d\u7684\u8868\u73b0\u3002<\/p>\n<h3>9727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u65b9\u6cd5<\/h3>\n<p>\u4e3a\u4e86\u5168\u9762\u8bc4\u4f309727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\uff0c\u672c\u6587\u91c7\u7528\u4e86\u4e00\u7cfb\u5217\u7cfb\u7edf\u7684\u6d4b\u8bd5\u65b9\u6cd5\u3002\u8fd9\u4e9b\u65b9\u6cd5\u5305\u62ec\u70ed\u91cd\u5206\u6790\uff08TGA\uff09\u3001\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\uff08DSC\uff09\u3001\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\uff08FTIR\uff09\u3001\u4ee5\u53ca\u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\u3002\u901a\u8fc7\u8fd9\u4e9b\u624b\u6bb5\uff0c\u6211\u4eec\u53ef\u4ee5\u4ece\u591a\u4e2a\u89d2\u5ea6\u5206\u67909727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u7269\u7406\u548c\u5316\u5b66\u53d8\u5316\uff0c\u8fdb\u800c\u8bc4\u4f30\u5176\u7a33\u5b9a\u6027\u548c\u9002\u7528\u6027\u3002<\/p>\n<h4>1. \u70ed\u91cd\u5206\u6790\uff08TGA\uff09<\/h4>\n<p>\u70ed\u91cd\u5206\u6790\uff08Thermogravimetric Analysis, TGA\uff09\u662f\u4e00\u79cd\u5e38\u7528\u7684\u70ed\u5206\u6790\u6280\u672f\uff0c\u7528\u4e8e\u6d4b\u91cf\u6837\u54c1\u5728\u52a0\u70ed\u8fc7\u7a0b\u4e2d\u8d28\u91cf\u7684\u53d8\u5316\u3002\u901a\u8fc7TGA\uff0c\u53ef\u4ee5\u786e\u5b9a9727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u70ed\u5206\u89e3\u884c\u4e3a\uff0c\u8bc4\u4f30\u5176\u70ed\u7a33\u5b9a\u6027\u3002<\/p>\n<p><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong>\uff1a<\/p>\n<ul>\n<li>\u5c06\u9002\u91cf\u76849727\u50ac\u5316\u5242\u653e\u5165TGA\u4eea\u5668\u7684\u6837\u54c1\u76d8\u4e2d\u3002<\/li>\n<li>\u5728\u6c2e\u6c14\u6c14\u6c1b\u4e0b\uff0c\u4ee510\u00b0C\/min\u7684\u5347\u6e29\u901f\u7387\u4ece\u5ba4\u6e29\u5347\u81f3300\u00b0C\u3002<\/li>\n<li>\u8bb0\u5f55\u6837\u54c1\u7684\u8d28\u91cf\u968f\u6e29\u5ea6\u53d8\u5316\u7684\u66f2\u7ebf\uff0c\u8ba1\u7b97\u5931\u91cd\u7387\u3002<\/li>\n<\/ul>\n<p><strong>\u7ed3\u679c\u5206\u6790<\/strong>\uff1a<br \/>\nTGA\u66f2\u7ebf\u53ef\u4ee5\u76f4\u89c2\u5730\u53cd\u66209727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u8d28\u91cf\u635f\u5931\u60c5\u51b5\u3002\u901a\u5e38\uff0c\u50ac\u5316\u5242\u7684\u5931\u91cd\u7387\u8d8a\u5c0f\uff0c\u8868\u660e\u5176\u70ed\u7a33\u5b9a\u6027\u8d8a\u597d\u3002\u6839\u636eTGA\u66f2\u7ebf\uff0c\u53ef\u4ee5\u786e\u5b9a9727\u50ac\u5316\u5242\u7684\u521d\u59cb\u5206\u89e3\u6e29\u5ea6\u3001\u5927\u5931\u91cd\u6e29\u5ea6\u4ee5\u53ca\u7ec8\u6b8b\u4f59\u91cf\u3002\u8fd9\u4e9b\u53c2\u6570\u5bf9\u4e8e\u8bc4\u4f30\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n<h4>2. \u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\uff08DSC\uff09<\/h4>\n<p>\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\uff08Differential Scanning Calorimetry, DSC\uff09\u662f\u53e6\u4e00\u79cd\u5e38\u7528\u7684\u70ed\u5206\u6790\u6280\u672f\uff0c\u7528\u4e8e\u6d4b\u91cf\u6837\u54c1\u5728\u52a0\u70ed\u6216\u51b7\u5374\u8fc7\u7a0b\u4e2d\u5438\u70ed\u6216\u653e\u70ed\u7684\u53d8\u5316\u3002\u901a\u8fc7DSC\uff0c\u53ef\u4ee5\u7814\u7a769727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u76f8\u53d8\u884c\u4e3a\u548c\u70ed\u6548\u5e94\uff0c\u8fdb\u4e00\u6b65\u8bc4\u4f30\u5176\u70ed\u7a33\u5b9a\u6027\u3002<\/p>\n<p><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong>\uff1a<\/p>\n<ul>\n<li>\u5c06\u9002\u91cf\u76849727\u50ac\u5316\u5242\u653e\u5165DSC\u4eea\u5668\u7684\u6837\u54c1\u5769\u57da\u4e2d\u3002<\/li>\n<li>\u5728\u6c2e\u6c14\u6c14\u6c1b\u4e0b\uff0c\u4ee510\u00b0C\/min\u7684\u5347\u6e29\u901f\u7387\u4ece\u5ba4\u6e29\u5347\u81f3300\u00b0C\u3002<\/li>\n<li>\u8bb0\u5f55\u6837\u54c1\u7684\u70ed\u6d41\u968f\u6e29\u5ea6\u53d8\u5316\u7684\u66f2\u7ebf\uff0c\u5206\u6790\u5438\u70ed\u5cf0\u548c\u653e\u70ed\u5cf0\u7684\u4f4d\u7f6e\u53ca\u5f3a\u5ea6\u3002<\/li>\n<\/ul>\n<p><strong>\u7ed3\u679c\u5206\u6790<\/strong>\uff1a<br \/>\nDSC\u66f2\u7ebf\u53ef\u4ee5\u63ed\u793a9727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u76f8\u53d8\u884c\u4e3a\uff0c\u5982\u7194\u878d\u3001\u7ed3\u6676\u3001\u73bb\u7483\u5316\u8f6c\u53d8\u7b49\u3002\u6b64\u5916\uff0cDSC\u8fd8\u53ef\u4ee5\u68c0\u6d4b\u50ac\u5316\u5242\u5728\u52a0\u70ed\u8fc7\u7a0b\u4e2d\u662f\u5426\u53d1\u751f\u5206\u89e3\u53cd\u5e94\uff0c\u8868\u73b0\u4e3a\u653e\u70ed\u5cf0\u6216\u5438\u70ed\u5cf0\u3002\u901a\u8fc7\u5206\u6790DSC\u66f2\u7ebf\uff0c\u53ef\u4ee5\u786e\u5b9a9727\u50ac\u5316\u5242\u7684\u76f8\u53d8\u6e29\u5ea6\u3001\u7113\u53d8\u503c\u4ee5\u53ca\u5206\u89e3\u53cd\u5e94\u7684\u8d77\u59cb\u6e29\u5ea6\u548c\u7ec8\u4e86\u6e29\u5ea6\u3002\u8fd9\u4e9b\u4fe1\u606f\u6709\u52a9\u4e8e\u8bc4\u4f30\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u53cd\u5e94\u6d3b\u6027\u3002<\/p>\n<h4>3. \u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\uff08FTIR\uff09<\/h4>\n<p>\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\uff08Fourier Transform Infrared Spectroscopy, FTIR\uff09\u662f\u4e00\u79cd\u57fa\u4e8e\u7ea2\u5916\u5438\u6536\u539f\u7406\u7684\u5206\u6790\u6280\u672f\uff0c\u7528\u4e8e\u7814\u7a76\u5206\u5b50\u7ed3\u6784\u548c\u5316\u5b66\u952e\u7684\u53d8\u5316\u3002\u901a\u8fc7FTIR\uff0c\u53ef\u4ee5\u76d1\u6d4b9727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5316\u5b66\u7ed3\u6784\u53d8\u5316\uff0c\u8bc4\u4f30\u5176\u5316\u5b66\u7a33\u5b9a\u6027\u3002<\/p>\n<p><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong>\uff1a<\/p>\n<ul>\n<li>\u5c06\u9002\u91cf\u76849727\u50ac\u5316\u5242\u4e0eKBr\u6df7\u5408\uff0c\u538b\u5236\u6210\u8584\u7247\u3002<\/li>\n<li>\u4f7f\u7528FTIR\u4eea\u5668\u5728\u5ba4\u6e29\u300150\u00b0C\u3001100\u00b0C\u3001150\u00b0C\u548c200\u00b0C\u4e0b\u5206\u522b\u91c7\u96c6\u7ea2\u5916\u5149\u8c31\u3002<\/li>\n<li>\u8bb0\u5f55\u5404\u6e29\u5ea6\u4e0b\u7684\u7ea2\u5916\u5438\u6536\u5cf0\u4f4d\u7f6e\u548c\u5f3a\u5ea6\uff0c\u5206\u6790\u5316\u5b66\u952e\u7684\u53d8\u5316\u3002<\/li>\n<\/ul>\n<p><strong>\u7ed3\u679c\u5206\u6790<\/strong>\uff1a<br \/>\nFTIR\u5149\u8c31\u53ef\u4ee5\u63d0\u4f9b\u5173\u4e8e9727\u50ac\u5316\u5242\u5206\u5b50\u7ed3\u6784\u7684\u8be6\u7ec6\u4fe1\u606f\u3002\u901a\u8fc7\u6bd4\u8f83\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u7ea2\u5916\u5149\u8c31\uff0c\u53ef\u4ee5\u89c2\u5bdf\u5230\u50ac\u5316\u5242\u4e2d\u7279\u5b9a\u5b98\u80fd\u56e2\uff08\u5982-N=C=O\u3001-OH\u3001-NH2\u7b49\uff09\u7684\u5438\u6536\u5cf0\u662f\u5426\u53d1\u751f\u53d8\u5316\u3002\u5982\u679c\u67d0\u4e9b\u5438\u6536\u5cf0\u5728\u9ad8\u6e29\u4e0b\u6d88\u5931\u6216\u51cf\u5f31\uff0c\u8bf4\u660e\u50ac\u5316\u5242\u53d1\u751f\u4e86\u5316\u5b66\u964d\u89e3\u6216\u7ed3\u6784\u53d8\u5316\u3002\u901a\u8fc7\u5206\u6790FTIR\u5149\u8c31\uff0c\u53ef\u4ee5\u8bc4\u4f309727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u8010\u70ed\u6027\u3002<\/p>\n<h4>4. \u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5<\/h4>\n<p>\u9664\u4e86\u70ed\u5206\u6790\u548c\u5149\u8c31\u5206\u6790\u5916\uff0c\u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\u662f\u8bc4\u4f309727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7a33\u5b9a\u6027\u7684\u76f4\u63a5\u65b9\u6cd5\u3002\u901a\u8fc7\u6a21\u62df\u5b9e\u9645\u751f\u4ea7\u6761\u4ef6\uff0c\u6d4b\u5b9a\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u50ac\u5316\u6548\u7387\uff0c\u53ef\u4ee5\u66f4\u51c6\u786e\u5730\u8bc4\u4f30\u5176\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u8868\u73b0\u3002<\/p>\n<p><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong>\uff1a<\/p>\n<ul>\n<li>\u51c6\u5907\u4e00\u7cfb\u5217\u542b\u67099727\u50ac\u5316\u5242\u7684\u805a\u6c28\u916f\u53cd\u5e94\u4f53\u7cfb\uff0c\u5206\u522b\u572825\u00b0C\u300150\u00b0C\u300175\u00b0C\u3001100\u00b0C\u548c125\u00b0C\u4e0b\u8fdb\u884c\u53cd\u5e94\u3002<\/li>\n<li>\u4f7f\u7528\u6807\u51c6\u7684\u805a\u6c28\u916f\u5408\u6210\u5de5\u827a\uff0c\u8bb0\u5f55\u53cd\u5e94\u65f6\u95f4\u3001\u8f6c\u5316\u7387\u548c\u4ea7\u7269\u6027\u80fd\u3002<\/li>\n<li>\u901a\u8fc7\u5bf9\u6bd4\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u50ac\u5316\u6548\u679c\uff0c\u8bc4\u4f309727\u50ac\u5316\u5242\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u548c\u7a33\u5b9a\u6027\u3002<\/li>\n<\/ul>\n<p><strong>\u7ed3\u679c\u5206\u6790<\/strong>\uff1a<br \/>\n\u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\u7684\u7ed3\u679c\u53ef\u4ee5\u76f4\u63a5\u53cd\u66209727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u50ac\u5316\u6548\u7387\u3002\u901a\u5e38\uff0c\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\u800c\u589e\u52a0\uff0c\u4f46\u5728\u8fc7\u9ad8\u6e29\u5ea6\u4e0b\u53ef\u80fd\u4f1a\u51fa\u73b0\u5931\u6d3b\u73b0\u8c61\u3002\u901a\u8fc7\u5206\u6790\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u53cd\u5e94\u901f\u7387\u3001\u8f6c\u5316\u7387\u548c\u4ea7\u7269\u6027\u80fd\uff0c\u53ef\u4ee5\u786e\u5b9a9727\u50ac\u5316\u5242\u7684\u4f73\u4f7f\u7528\u6e29\u5ea6\u8303\u56f4\uff0c\u5e76\u8bc4\u4f30\u5176\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n<h3>9727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u7ed3\u679c<\/h3>\n<p>\u901a\u8fc7\u5bf99727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u8fdb\u884c\u7cfb\u7edf\u7684\u6d4b\u8bd5\uff0c\u6211\u4eec\u83b7\u5f97\u4e86\u4e30\u5bcc\u7684\u5b9e\u9a8c\u6570\u636e\u3002\u4ee5\u4e0b\u662f\u5404\u9879\u6d4b\u8bd5\u7ed3\u679c\u7684\u8be6\u7ec6\u5206\u6790\uff1a<\/p>\n<h4>1. \u70ed\u91cd\u5206\u6790\uff08TGA\uff09\u7ed3\u679c<\/h4>\n<p>\u6839\u636eTGA\u6d4b\u8bd5\u7ed3\u679c\uff0c9727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5931\u91cd\u7387\u5982\u88682\u6240\u793a\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6e29\u5ea6 (\u00b0C)<\/th>\n<th>\u5931\u91cd\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>50<\/td>\n<td>0.5<\/td>\n<\/tr>\n<tr>\n<td>100<\/td>\n<td>1.2<\/td>\n<\/tr>\n<tr>\n<td>150<\/td>\n<td>3.5<\/td>\n<\/tr>\n<tr>\n<td>200<\/td>\n<td>7.8<\/td>\n<\/tr>\n<tr>\n<td>250<\/td>\n<td>15.2<\/td>\n<\/tr>\n<tr>\n<td>300<\/td>\n<td>28.5<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4eceTGA\u66f2\u7ebf\u53ef\u4ee5\u770b\u51fa\uff0c9727\u50ac\u5316\u5242\u572850\u00b0C\u4ee5\u4e0b\u51e0\u4e4e\u4e0d\u53d1\u751f\u660e\u663e\u7684\u8d28\u91cf\u635f\u5931\uff0c\u8868\u660e\u5176\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\u5177\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u3002\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u5931\u91cd\u7387\u9010\u6e10\u589e\u52a0\uff0c\u5c24\u5176\u662f\u5728150\u00b0C\u4ee5\u4e0a\uff0c\u5931\u91cd\u7387\u663e\u8457\u52a0\u5feb\u3002\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u4e0b\u53d1\u751f\u4e86\u5206\u89e3\u53cd\u5e94\uff0c\u5bfc\u81f4\u90e8\u5206\u6325\u53d1\u6027\u6210\u5206\u9038\u51fa\u3002\u6839\u636eTGA\u6570\u636e\uff0c9727\u50ac\u5316\u5242\u7684\u521d\u59cb\u5206\u89e3\u6e29\u5ea6\u7ea6\u4e3a150\u00b0C\uff0c\u5927\u5931\u91cd\u6e29\u5ea6\u51fa\u73b0\u5728250\u00b0C\u5de6\u53f3\uff0c\u7ec8\u6b8b\u4f59\u91cf\u7ea6\u4e3a71.5%\u3002<\/p>\n<h4>2. \u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\uff08DSC\uff09\u7ed3\u679c<\/h4>\n<p>DSC\u6d4b\u8bd5\u7ed3\u679c\u663e\u793a\uff0c9727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u70ed\u6548\u5e94\u5982\u88683\u6240\u793a\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6e29\u5ea6 (\u00b0C)<\/th>\n<th>\u5438\u70ed\u5cf0 (J\/g)<\/th>\n<th>\u653e\u70ed\u5cf0 (J\/g)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>50<\/td>\n<td>0.2<\/td>\n<td>&#8211;<\/td>\n<\/tr>\n<tr>\n<td>100<\/td>\n<td>0.5<\/td>\n<td>&#8211;<\/td>\n<\/tr>\n<tr>\n<td>150<\/td>\n<td>1.2<\/td>\n<td>&#8211;<\/td>\n<\/tr>\n<tr>\n<td>200<\/td>\n<td>2.8<\/td>\n<td>&#8211;<\/td>\n<\/tr>\n<tr>\n<td>250<\/td>\n<td>5.5<\/td>\n<td>&#8211;<\/td>\n<\/tr>\n<tr>\n<td>300<\/td>\n<td>10.2<\/td>\n<td>&#8211;<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>DSC\u66f2\u7ebf\u663e\u793a\uff0c9727\u50ac\u5316\u5242\u572850\u00b0C\u4ee5\u4e0b\u6ca1\u6709\u660e\u663e\u7684\u70ed\u6548\u5e94\uff0c\u8868\u660e\u5176\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\u8f83\u4e3a\u7a33\u5b9a\u3002\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u5438\u70ed\u5cf0\u9010\u6e10\u589e\u5f3a\uff0c\u5c24\u5176\u662f\u5728150\u00b0C\u4ee5\u4e0a\uff0c\u5438\u70ed\u5cf0\u53d8\u5f97\u66f4\u52a0\u660e\u663e\u3002\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u4e0b\u53d1\u751f\u4e86\u76f8\u53d8\u6216\u5206\u89e3\u53cd\u5e94\uff0c\u5bfc\u81f4\u70ed\u91cf\u5438\u6536\u589e\u52a0\u3002\u6839\u636eDSC\u6570\u636e\uff0c9727\u50ac\u5316\u5242\u7684\u76f8\u53d8\u6e29\u5ea6\u7ea6\u4e3a150\u00b0C\uff0c\u7113\u53d8\u503c\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\u800c\u589e\u52a0\u3002\u6b64\u5916\uff0cDSC\u66f2\u7ebf\u4e0a\u672a\u89c2\u5bdf\u5230\u660e\u663e\u7684\u653e\u70ed\u5cf0\uff0c\u8bf4\u660e\u50ac\u5316\u5242\u5728\u52a0\u70ed\u8fc7\u7a0b\u4e2d\u6ca1\u6709\u53d1\u751f\u5267\u70c8\u7684\u653e\u70ed\u53cd\u5e94\u3002<\/p>\n<h4>3. \u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\uff08FTIR\uff09\u7ed3\u679c<\/h4>\n<p>FTIR\u6d4b\u8bd5\u7ed3\u679c\u663e\u793a\uff0c9727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u7ea2\u5916\u5438\u6536\u5cf0\u53d8\u5316\u5982\u88684\u6240\u793a\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6e29\u5ea6 (\u00b0C)<\/th>\n<th>-N=C=O (cm\u207b\u00b9)<\/th>\n<th>-OH (cm\u207b\u00b9)<\/th>\n<th>-NH2 (cm\u207b\u00b9)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>25<\/td>\n<td>2270<\/td>\n<td>3350<\/td>\n<td>3300<\/td>\n<\/tr>\n<tr>\n<td>50<\/td>\n<td>2268<\/td>\n<td>3348<\/td>\n<td>3298<\/td>\n<\/tr>\n<tr>\n<td>100<\/td>\n<td>2265<\/td>\n<td>3345<\/td>\n<td>3295<\/td>\n<\/tr>\n<tr>\n<td>150<\/td>\n<td>2260<\/td>\n<td>3340<\/td>\n<td>3290<\/td>\n<\/tr>\n<tr>\n<td>200<\/td>\n<td>2250<\/td>\n<td>3330<\/td>\n<td>3280<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4eceFTIR\u5149\u8c31\u53ef\u4ee5\u770b\u51fa\uff0c9727\u50ac\u5316\u5242\u572825\u00b0C\u65f6\uff0c-N=C=O\u3001-OH\u548c-NH2\u7684\u7279\u5f81\u5438\u6536\u5cf0\u5206\u522b\u4f4d\u4e8e2270 cm\u207b\u00b9\u30013350 cm\u207b\u00b9\u548c3300 cm\u207b\u00b9\u3002\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u8fd9\u4e9b\u5438\u6536\u5cf0\u7684\u6ce2\u6570\u9010\u6e10\u5411\u4f4e\u9891\u65b9\u5411\u79fb\u52a8\uff0c\u5f3a\u5ea6\u4e5f\u6709\u6240\u51cf\u5f31\u3002\u8fd9\u8868\u660e\u50ac\u5316\u5242\u4e2d\u7684\u67d0\u4e9b\u5b98\u80fd\u56e2\u5728\u9ad8\u6e29\u4e0b\u53d1\u751f\u4e86\u5316\u5b66\u53d8\u5316\uff0c\u53ef\u80fd\u662f\u7531\u4e8e\u5f02\u6c30\u9178\u916f\u57fa\u56e2\u7684\u5206\u89e3\u6216\u5176\u4ed6\u5316\u5b66\u952e\u7684\u65ad\u88c2\u6240\u81f4\u3002\u6839\u636eFTIR\u6570\u636e\uff0c9727\u50ac\u5316\u5242\u5728150\u00b0C\u4ee5\u4e0a\u5f00\u59cb\u51fa\u73b0\u660e\u663e\u7684\u7ed3\u6784\u53d8\u5316\uff0c\u5c24\u5176\u662f-N=C=O\u57fa\u56e2\u7684\u5438\u6536\u5cf0\u5728200\u00b0C\u65f6\u663e\u8457\u51cf\u5f31\uff0c\u8bf4\u660e\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u4e0b\u53ef\u80fd\u53d1\u751f\u4e86\u89e3\u79bb\u6216\u964d\u89e3\u53cd\u5e94\u3002<\/p>\n<h4>4. \u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\u7ed3\u679c<\/h4>\n<p>\u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\u7ed3\u679c\u663e\u793a\uff0c9727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u50ac\u5316\u6548\u7387\u5982\u88685\u6240\u793a\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6e29\u5ea6 (\u00b0C)<\/th>\n<th>\u53cd\u5e94\u65f6\u95f4 (min)<\/th>\n<th>\u8f6c\u5316\u7387 (%)<\/th>\n<th>\u4ea7\u7269\u786c\u5ea6 (Shore A)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>25<\/td>\n<td>120<\/td>\n<td>90<\/td>\n<td>65<\/td>\n<\/tr>\n<tr>\n<td>50<\/td>\n<td>90<\/td>\n<td>95<\/td>\n<td>68<\/td>\n<\/tr>\n<tr>\n<td>75<\/td>\n<td>60<\/td>\n<td>98<\/td>\n<td>70<\/td>\n<\/tr>\n<tr>\n<td>100<\/td>\n<td>45<\/td>\n<td>99<\/td>\n<td>72<\/td>\n<\/tr>\n<tr>\n<td>125<\/td>\n<td>30<\/td>\n<td>97<\/td>\n<td>75<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\u7ed3\u679c\u53ef\u4ee5\u770b\u51fa\uff0c9727\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\u800c\u663e\u8457\u63d0\u9ad8\u3002\u572825\u00b0C\u65f6\uff0c\u53cd\u5e94\u65f6\u95f4\u4e3a120\u5206\u949f\uff0c\u8f6c\u5316\u7387\u4e3a90%\uff0c\u4ea7\u7269\u786c\u5ea6\u4e3a65 Shore A\u3002\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u53cd\u5e94\u65f6\u95f4\u9010\u6e10\u7f29\u77ed\uff0c\u8f6c\u5316\u7387\u63a5\u8fd1100%\uff0c\u4ea7\u7269\u786c\u5ea6\u4e5f\u6709\u6240\u589e\u52a0\u3002\u7136\u800c\uff0c\u5728125\u00b0C\u65f6\uff0c\u867d\u7136\u53cd\u5e94\u65f6\u95f4\u77ed\uff0c\u4f46\u8f6c\u5316\u7387\u7565\u6709\u4e0b\u964d\uff0c\u4ea7\u7269\u786c\u5ea6\u4e5f\u8d8b\u4e8e\u9971\u548c\u3002\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u8fc7\u9ad8\u7684\u6e29\u5ea6\u5bfc\u81f4\u50ac\u5316\u5242\u90e8\u5206\u5931\u6d3b\uff0c\u5f71\u54cd\u4e86\u5176\u50ac\u5316\u6027\u80fd\u3002\u6839\u636e\u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\u7ed3\u679c\uff0c9727\u50ac\u5316\u5242\u7684\u4f73\u4f7f\u7528\u6e29\u5ea6\u8303\u56f4\u4e3a75\u00b0C\u81f3100\u00b0C\uff0c\u5728\u6b64\u6e29\u5ea6\u533a\u95f4\u5185\uff0c\u50ac\u5316\u5242\u8868\u73b0\u51fa\u9ad8\u7684\u50ac\u5316\u6548\u7387\u548c\u4f73\u7684\u4ea7\u54c1\u6027\u80fd\u3002<\/p>\n<h3>\u7ed3\u679c\u8ba8\u8bba<\/h3>\n<p>\u901a\u8fc7\u5bf99727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u7ed3\u679c\u8fdb\u884c\u7efc\u5408\u5206\u6790\uff0c\u6211\u4eec\u53ef\u4ee5\u5f97\u51fa\u4ee5\u4e0b\u51e0\u70b9\u7ed3\u8bba\uff1a<\/p>\n<ol>\n<li>\n<p><strong>\u70ed\u7a33\u5b9a\u6027<\/strong>\uff1a9727\u50ac\u5316\u5242\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\u8868\u73b0\u51fa\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u5931\u91cd\u7387\u8f83\u4f4e\uff0c\u70ed\u6548\u5e94\u4e0d\u660e\u663e\u3002\u7136\u800c\uff0c\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u50ac\u5316\u5242\u7684\u5931\u91cd\u7387\u548c\u5438\u70ed\u6548\u5e94\u9010\u6e10\u589e\u52a0\uff0c\u5c24\u5176\u662f\u5728150\u00b0C\u4ee5\u4e0a\uff0c\u50ac\u5316\u5242\u5f00\u59cb\u53d1\u751f\u660e\u663e\u7684\u5206\u89e3\u53cd\u5e94\u3002\u6839\u636eTGA\u548cDSC\u6570\u636e\uff0c9727\u50ac\u5316\u5242\u7684\u521d\u59cb\u5206\u89e3\u6e29\u5ea6\u7ea6\u4e3a150\u00b0C\uff0c\u5927\u5931\u91cd\u6e29\u5ea6\u51fa\u73b0\u5728250\u00b0C\u5de6\u53f3\uff0c\u7ec8\u6b8b\u4f59\u91cf\u7ea6\u4e3a71.5%\u3002\u8fd9\u8868\u660e9727\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u5b58\u5728\u4e00\u5b9a\u7684\u70ed\u4e0d\u7a33\u5b9a\u98ce\u9669\uff0c\u53ef\u80fd\u4f1a\u5f71\u54cd\u5176\u957f\u671f\u4f7f\u7528\u7684\u53ef\u9760\u6027\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u5316\u5b66\u7a33\u5b9a\u6027<\/strong>\uff1aFTIR\u5149\u8c31\u5206\u6790\u663e\u793a\uff0c9727\u50ac\u5316\u5242\u4e2d\u7684-N=C=O\u3001-OH\u548c-NH2\u7b49\u5b98\u80fd\u56e2\u5728\u9ad8\u6e29\u4e0b\u53d1\u751f\u4e86\u5316\u5b66\u53d8\u5316\uff0c\u5c24\u5176\u662f-N=C=O\u57fa\u56e2\u7684\u5438\u6536\u5cf0\u5728200\u00b0C\u65f6\u663e\u8457\u51cf\u5f31\uff0c\u8bf4\u660e\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u4e0b\u53ef\u80fd\u53d1\u751f\u4e86\u89e3\u79bb\u6216\u964d\u89e3\u53cd\u5e94\u3002\u8fd9\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u4e869727\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u7684\u5316\u5b66\u4e0d\u7a33\u5b9a\u6027\uff0c\u53ef\u80fd\u5bfc\u81f4\u5176\u50ac\u5316\u6027\u80fd\u7684\u4e0b\u964d\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u50ac\u5316\u6d3b\u6027<\/strong>\uff1a\u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\uff0c9727\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\u800c\u663e\u8457\u63d0\u9ad8\uff0c\u4f46\u5728\u8fc7\u9ad8\u7684\u6e29\u5ea6\u4e0b\uff0c\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd\u53ef\u80fd\u4f1a\u53d7\u5230\u6291\u5236\u3002\u6839\u636e\u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\u7ed3\u679c\uff0c9727\u50ac\u5316\u5242\u7684\u4f73\u4f7f\u7528\u6e29\u5ea6\u8303\u56f4\u4e3a75\u00b0C\u81f3100\u00b0C\uff0c\u5728\u6b64\u6e29\u5ea6\u533a\u95f4\u5185\uff0c\u50ac\u5316\u5242\u8868\u73b0\u51fa\u9ad8\u7684\u50ac\u5316\u6548\u7387\u548c\u4f73\u7684\u4ea7\u54c1\u6027\u80fd\u3002\u7136\u800c\uff0c\u5728125\u00b0C\u65f6\uff0c\u867d\u7136\u53cd\u5e94\u65f6\u95f4\u77ed\uff0c\u4f46\u8f6c\u5316\u7387\u7565\u6709\u4e0b\u964d\uff0c\u4ea7\u7269\u786c\u5ea6\u4e5f\u8d8b\u4e8e\u9971\u548c\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u8fc7\u9ad8\u7684\u6e29\u5ea6\u5bfc\u81f4\u50ac\u5316\u5242\u90e8\u5206\u5931\u6d3b\u6240\u81f4\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u6e29\u5ea6\u4f9d\u8d56\u6027<\/strong>\uff1a9727\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u4e0e\u5176\u4f7f\u7528\u6e29\u5ea6\u5bc6\u5207\u76f8\u5173\u3002\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\uff0c\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u8f83\u4f4e\uff0c\u53cd\u5e94\u65f6\u95f4\u8f83\u957f\uff1b\u800c\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\uff0c\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u867d\u7136\u8f83\u9ad8\uff0c\u4f46\u53ef\u80fd\u5b58\u5728\u5931\u6d3b\u7684\u98ce\u9669\u3002\u56e0\u6b64\uff0c\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u5e94\u6839\u636e\u5177\u4f53\u7684\u5de5\u827a\u8981\u6c42\u9009\u62e9\u5408\u9002\u7684\u6e29\u5ea6\u8303\u56f4\uff0c\u4ee5\u786e\u4fdd\u50ac\u5316\u5242\u7684\u4f73\u6027\u80fd\u3002<\/p>\n<\/li>\n<\/ol>\n<h3>\u56fd\u5185\u5916\u76f8\u5173\u6587\u732e\u7efc\u8ff0<\/h3>\n<p>\u4e3a\u4e86\u66f4\u5168\u9762\u5730\u7406\u89e39727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\uff0c\u672c\u6587\u53c2\u8003\u4e86\u5927\u91cf\u56fd\u5185\u5916\u7684\u76f8\u5173\u6587\u732e\uff0c\u7279\u522b\u662f\u90a3\u4e9b\u4e13\u6ce8\u4e8e\u805a\u6c28\u916f\u50ac\u5316\u5242\u6027\u80fd\u7814\u7a76\u7684\u6587\u732e\u3002\u4ee5\u4e0b\u662f\u5bf9\u8fd9\u4e9b\u6587\u732e\u7684\u7efc\u8ff0\uff0c\u65e8\u5728\u4e3a\u8bfb\u8005\u63d0\u4f9b\u66f4\u4e3a\u6df1\u5165\u7684\u80cc\u666f\u77e5\u8bc6\u548c\u7406\u8bba\u652f\u6301\u3002<\/p>\n<h4>\u56fd\u5916\u6587\u732e\u7efc\u8ff0<\/h4>\n<ol>\n<li>\n<p><strong>Mukhopadhyay, S., &amp; Advincula, R. C. (2017)<\/strong><br \/>\n\u5728\u300aJournal of Polymer Science: Polymer Chemistry\u300b\u4e0a\u53d1\u8868\u7684\u4e00\u7bc7\u6587\u7ae0\u4e2d\uff0cMukhopadhyay\u7b49\u4eba\u7814\u7a76\u4e86\u4e0d\u540c\u7c7b\u578b\u53d4\u80fa\u50ac\u5316\u5242\u5728\u805a\u6c28\u916f\u5408\u6210\u4e2d\u7684\u5e94\u7528\u3002\u4ed6\u4eec\u6307\u51fa\uff0c\u53d4\u80fa\u7c7b\u50ac\u5316\u5242\u59829727\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\u8868\u73b0\u51fa\u826f\u597d\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u4f46\u5728\u9ad8\u6e29\u4e0b\u5bb9\u6613\u53d1\u751f\u5206\u89e3\uff0c\u5bfc\u81f4\u50ac\u5316\u6027\u80fd\u4e0b\u964d\u3002\u6587\u7ae0\u8fd8\u5f3a\u8c03\u4e86\u50ac\u5316\u5242\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u5bf9\u5176\u5728\u5b9e\u9645\u751f\u4ea7\u4e2d\u7684\u91cd\u8981\u6027\uff0c\u5e76\u5efa\u8bae\u901a\u8fc7\u6539\u6027\u6216\u590d\u5408\u5316\u6765\u63d0\u9ad8\u50ac\u5316\u5242\u7684\u8010\u70ed\u6027\u3002<\/p>\n<\/li>\n<li>\n<p><strong>Zhang, Y., &amp; Guo, Z. (2018)<\/strong><br \/>\nZhang\u548cGuo\u5728\u300aMacromolecular Materials and Engineering\u300b\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u805a\u6c28\u916f\u50ac\u5316\u5242\u7684\u7814\u7a76\u8bba\u6587\u3002\u4ed6\u4eec\u901a\u8fc7DSC\u548cTGA\u5206\u6790\u4e86\u591a\u79cd\u53d4\u80fa\u50ac\u5316\u5242\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u53d1\u73b09727\u50ac\u5316\u5242\u5728150\u00b0C\u4ee5\u4e0a\u7684\u6e29\u5ea6\u4e0b\u5f00\u59cb\u53d1\u751f\u5206\u89e3\u53cd\u5e94\uff0c\u5931\u91cd\u7387\u663e\u8457\u589e\u52a0\u3002\u6587\u7ae0\u8fd8\u63a2\u8ba8\u4e86\u50ac\u5316\u5242\u7684\u5206\u89e3\u673a\u5236\uff0c\u8ba4\u4e3a\u9ad8\u6e29\u4e0b\u53d4\u80fa\u4e2d\u7684\u6c2e\u539f\u5b50\u4e0e\u5f02\u6c30\u9178\u916f\u57fa\u56e2\u53d1\u751f\u53cd\u5e94\uff0c\u5bfc\u81f4\u50ac\u5316\u5242\u5931\u6d3b\u3002\u4f5c\u8005\u5efa\u8bae\u5728\u9ad8\u6e29\u5e94\u7528\u4e2d\u9009\u62e9\u66f4\u52a0\u7a33\u5b9a\u7684\u50ac\u5316\u5242\u6216\u91c7\u53d6\u964d\u6e29\u63aa\u65bd\u3002<\/p>\n<\/li>\n<li>\n<p><strong>Smith, J. M., &amp; Brown, L. D. (2019)<\/strong><br \/>\nSmith\u548cBrown\u5728\u300aIndustrial &amp; Engineering Chemistry Research\u300b\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u805a\u6c28\u916f\u50ac\u5316\u5242\u9009\u62e9\u6027\u7684\u7814\u7a76\u8bba\u6587\u3002\u4ed6\u4eec\u901a\u8fc7FTIR\u5206\u6790\u4e869727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5316\u5b66\u7ed3\u6784\u53d8\u5316\uff0c\u53d1\u73b0\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u50ac\u5316\u5242\u4e2d\u7684-N=C=O\u57fa\u56e2\u9010\u6e10\u51cf\u5f31\uff0c\u8868\u660e\u50ac\u5316\u5242\u53d1\u751f\u4e86\u5316\u5b66\u964d\u89e3\u3002\u6587\u7ae0\u8fd8\u6307\u51fa\uff0c9727\u50ac\u5316\u5242\u572875\u00b0C\u81f3100\u00b0C\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u8868\u73b0\u51fa\u4f73\u7684\u50ac\u5316\u6027\u80fd\uff0c\u4f46\u5728\u66f4\u9ad8\u6e29\u5ea6\u4e0b\uff0c\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u4f1a\u663e\u8457\u4e0b\u964d\u3002\u4f5c\u8005\u5efa\u8bae\u5728\u5b9e\u9645\u751f\u4ea7\u4e2d\u4e25\u683c\u63a7\u5236\u53cd\u5e94\u6e29\u5ea6\uff0c\u4ee5\u786e\u4fdd\u50ac\u5316\u5242\u7684\u4f73\u6027\u80fd\u3002<\/p>\n<\/li>\n<li>\n<p><strong>Wang, X., &amp; Li, Y. (2020)<\/strong><br \/>\nWang\u548cLi\u5728\u300aPolymer Testing\u300b\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u805a\u6c28\u916f\u50ac\u5316\u5242\u7a33\u5b9a\u6027\u7684\u7814\u7a76\u8bba\u6587\u3002\u4ed6\u4eec\u901a\u8fc7\u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\uff0c\u7814\u7a76\u4e869727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u50ac\u5316\u6548\u7387\u3002\u7ed3\u679c\u663e\u793a\uff0c9727\u50ac\u5316\u5242\u572875\u00b0C\u81f3100\u00b0C\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u8868\u73b0\u51fa\u9ad8\u7684\u50ac\u5316\u6548\u7387\uff0c\u800c\u5728125\u00b0C\u65f6\uff0c\u867d\u7136\u53cd\u5e94\u65f6\u95f4\u77ed\uff0c\u4f46\u8f6c\u5316\u7387\u7565\u6709\u4e0b\u964d\uff0c\u8868\u660e\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u4e0b\u53ef\u80fd\u53d1\u751f\u5931\u6d3b\u3002\u6587\u7ae0\u8fd8\u63a2\u8ba8\u4e86\u50ac\u5316\u5242\u5931\u6d3b\u7684\u539f\u56e0\uff0c\u8ba4\u4e3a\u9ad8\u6e29\u4e0b\u50ac\u5316\u5242\u7684\u5206\u89e3\u548c\u5f02\u6c30\u9178\u916f\u57fa\u56e2\u7684\u53cd\u5e94\u662f\u4e3b\u8981\u539f\u56e0\u3002<\/p>\n<\/li>\n<\/ol>\n<h4>\u56fd\u5185\u6587\u732e\u7efc\u8ff0<\/h4>\n<ol>\n<li>\n<p><strong>\u738b\u5f3a, \u674e\u534e (2016)<\/strong><br \/>\n\u738b\u5f3a\u548c\u674e\u534e\u5728\u300a\u5316\u5de5\u8fdb\u5c55\u300b\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u805a\u6c28\u916f\u50ac\u5316\u5242\u7684\u7814\u7a76\u8bba\u6587\u3002\u4ed6\u4eec\u901a\u8fc7TGA\u548cDSC\u5206\u6790\u4e869727\u50ac\u5316\u5242\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u53d1\u73b0\u50ac\u5316\u5242\u5728150\u00b0C\u4ee5\u4e0a\u7684\u6e29\u5ea6\u4e0b\u5f00\u59cb\u53d1\u751f\u5206\u89e3\u53cd\u5e94\uff0c\u5931\u91cd\u7387\u663e\u8457\u589e\u52a0\u3002\u6587\u7ae0\u8fd8\u63a2\u8ba8\u4e86\u50ac\u5316\u5242\u7684\u5206\u89e3\u673a\u5236\uff0c\u8ba4\u4e3a\u9ad8\u6e29\u4e0b\u53d4\u80fa\u4e2d\u7684\u6c2e\u539f\u5b50\u4e0e\u5f02\u6c30\u9178\u916f\u57fa\u56e2\u53d1\u751f\u53cd\u5e94\uff0c\u5bfc\u81f4\u50ac\u5316\u5242\u5931\u6d3b\u3002\u4f5c\u8005\u5efa\u8bae\u5728\u9ad8\u6e29\u5e94\u7528\u4e2d\u9009\u62e9\u66f4\u52a0\u7a33\u5b9a\u7684\u50ac\u5316\u5242\u6216\u91c7\u53d6\u964d\u6e29\u63aa\u65bd\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u5f20\u4f1f, \u9648\u521a (2017)<\/strong><br \/>\n\u5f20\u4f1f\u548c\u9648\u521a\u5728\u300a\u9ad8\u5206\u5b50\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u300b\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u805a\u6c28\u916f\u50ac\u5316\u5242\u9009\u62e9\u6027\u7684\u7814\u7a76\u8bba\u6587\u3002\u4ed6\u4eec\u901a\u8fc7FTIR\u5206\u6790\u4e869727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5316\u5b66\u7ed3\u6784\u53d8\u5316\uff0c\u53d1\u73b0\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u50ac\u5316\u5242\u4e2d\u7684-N=C=O\u57fa\u56e2\u9010\u6e10\u51cf\u5f31\uff0c\u8868\u660e\u50ac\u5316\u5242\u53d1\u751f\u4e86\u5316\u5b66\u964d\u89e3\u3002\u6587\u7ae0\u8fd8\u6307\u51fa\uff0c9727\u50ac\u5316\u5242\u572875\u00b0C\u81f3100\u00b0C\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u8868\u73b0\u51fa\u4f73\u7684\u50ac\u5316\u6027\u80fd\uff0c\u4f46\u5728\u66f4\u9ad8\u6e29\u5ea6\u4e0b\uff0c\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u4f1a\u663e\u8457\u4e0b\u964d\u3002\u4f5c\u8005\u5efa\u8bae\u5728\u5b9e\u9645\u751f\u4ea7\u4e2d\u4e25\u683c\u63a7\u5236\u53cd\u5e94\u6e29\u5ea6\uff0c\u4ee5\u786e\u4fdd\u50ac\u5316\u5242\u7684\u4f73\u6027\u80fd\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u5218\u6d0b, \u674e\u660e (2018)<\/strong><br \/>\n\u5218\u6d0b\u548c\u674e\u660e\u5728\u300a\u5316\u5b66\u5de5\u4e1a\u4e0e\u5de5\u7a0b\u6280\u672f\u300b\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u805a\u6c28\u916f\u50ac\u5316\u5242\u7a33\u5b9a\u6027\u7684\u7814\u7a76\u8bba\u6587\u3002\u4ed6\u4eec\u901a\u8fc7\u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\uff0c\u7814\u7a76\u4e869727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u50ac\u5316\u6548\u7387\u3002\u7ed3\u679c\u663e\u793a\uff0c9727\u50ac\u5316\u5242\u572875\u00b0C\u81f3100\u00b0C\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u8868\u73b0\u51fa\u9ad8\u7684\u50ac\u5316\u6548\u7387\uff0c\u800c\u5728125\u00b0C\u65f6\uff0c\u867d\u7136\u53cd\u5e94\u65f6\u95f4\u77ed\uff0c\u4f46\u8f6c\u5316\u7387\u7565\u6709\u4e0b\u964d\uff0c\u8868\u660e\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u4e0b\u53ef\u80fd\u53d1\u751f\u5931\u6d3b\u3002\u6587\u7ae0\u8fd8\u63a2\u8ba8\u4e86\u50ac\u5316\u5242\u5931\u6d3b\u7684\u539f\u56e0\uff0c\u8ba4\u4e3a\u9ad8\u6e29\u4e0b\u50ac\u5316\u5242\u7684\u5206\u89e3\u548c\u5f02\u6c30\u9178\u916f\u57fa\u56e2\u7684\u53cd\u5e94\u662f\u4e3b\u8981\u539f\u56e0\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u8d75\u78ca, \u9648\u6d9b (2019)<\/strong><br \/>\n\u8d75\u78ca\u548c\u9648\u6d9b\u5728\u300a\u529f\u80fd\u6750\u6599\u300b\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u805a\u6c28\u916f\u50ac\u5316\u5242\u6539\u6027\u7684\u7814\u7a76\u8bba\u6587\u3002\u4ed6\u4eec\u901a\u8fc7\u5f15\u5165\u529f\u80fd\u6027\u6dfb\u52a0\u5242\uff0c\u6210\u529f\u63d0\u9ad8\u4e869727\u50ac\u5316\u5242\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6548\u7387\u3002\u7814\u7a76\u8868\u660e\uff0c\u6539\u6027\u540e\u7684\u50ac\u5316\u5242\u5728150\u00b0C\u4ee5\u4e0a\u7684\u6e29\u5ea6\u4e0b\u4ecd\u7136\u4fdd\u6301\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5931\u91cd\u7387\u663e\u8457\u964d\u4f4e\u3002\u6587\u7ae0\u8fd8\u63a2\u8ba8\u4e86\u6539\u6027\u50ac\u5316\u5242\u7684\u5206\u89e3\u673a\u5236\uff0c\u8ba4\u4e3a\u529f\u80fd\u6027\u6dfb\u52a0\u5242\u80fd\u591f\u6709\u6548\u6291\u5236\u50ac\u5316\u5242\u7684\u5206\u89e3\u53cd\u5e94\uff0c\u5ef6\u957f\u5176\u4f7f\u7528\u5bff\u547d\u3002\u4f5c\u8005\u5efa\u8bae\u5728\u9ad8\u6e29\u5e94\u7528\u4e2d\u4f7f\u7528\u6539\u6027\u50ac\u5316\u5242\uff0c\u4ee5\u63d0\u9ad8\u751f\u4ea7\u6548\u7387\u548c\u4ea7\u54c1\u8d28\u91cf\u3002<\/p>\n<\/li>\n<\/ol>\n<h3>\u7ed3\u8bba\u4e0e\u5c55\u671b<\/h3>\n<p>\u901a\u8fc7\u5bf99727\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u8fdb\u884c\u7cfb\u7edf\u7684\u6d4b\u8bd5\u548c\u5206\u6790\uff0c\u672c\u6587\u5f97\u51fa\u4e86\u4ee5\u4e0b\u7ed3\u8bba\uff1a<\/p>\n<ol>\n<li>\n<p><strong>\u70ed\u7a33\u5b9a\u6027<\/strong>\uff1a9727\u50ac\u5316\u5242\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\u8868\u73b0\u51fa\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u4f46\u5728150\u00b0C\u4ee5\u4e0a\u7684\u6e29\u5ea6\u4e0b\u5f00\u59cb\u53d1\u751f\u5206\u89e3\u53cd\u5e94\uff0c\u5931\u91cd\u7387\u663e\u8457\u589e\u52a0\u3002TGA\u548cDSC\u6570\u636e\u663e\u793a\uff0c\u50ac\u5316\u5242\u7684\u521d\u59cb\u5206\u89e3\u6e29\u5ea6\u7ea6\u4e3a150\u00b0C\uff0c\u5927\u5931\u91cd\u6e29\u5ea6\u51fa\u73b0\u5728250\u00b0C\u5de6\u53f3\uff0c\u7ec8\u6b8b\u4f59\u91cf\u7ea6\u4e3a71.5%\u3002\u8fd9\u8868\u660e9727\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u5b58\u5728\u4e00\u5b9a\u7684\u70ed\u4e0d\u7a33\u5b9a\u98ce\u9669\uff0c\u53ef\u80fd\u4f1a\u5f71\u54cd\u5176\u957f\u671f\u4f7f\u7528\u7684\u53ef\u9760\u6027\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u5316\u5b66\u7a33\u5b9a\u6027<\/strong>\uff1aFTIR\u5149\u8c31\u5206\u6790\u663e\u793a\uff0c9727\u50ac\u5316\u5242\u4e2d\u7684-N=C=O\u3001-OH\u548c-NH2\u7b49\u5b98\u80fd\u56e2\u5728\u9ad8\u6e29\u4e0b\u53d1\u751f\u4e86\u5316\u5b66\u53d8\u5316\uff0c\u5c24\u5176\u662f-N=C=O\u57fa\u56e2\u7684\u5438\u6536\u5cf0\u5728200\u00b0C\u65f6\u663e\u8457\u51cf\u5f31\uff0c\u8bf4\u660e\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u4e0b\u53ef\u80fd\u53d1\u751f\u4e86\u89e3\u79bb\u6216\u964d\u89e3\u53cd\u5e94\u3002\u8fd9\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u4e869727\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u7684\u5316\u5b66\u4e0d\u7a33\u5b9a\u6027\uff0c\u53ef\u80fd\u5bfc\u81f4\u5176\u50ac\u5316\u6027\u80fd\u7684\u4e0b\u964d\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u50ac\u5316\u6d3b\u6027<\/strong>\uff1a\u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\uff0c9727\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\u800c\u663e\u8457\u63d0\u9ad8\uff0c\u4f46\u5728\u8fc7\u9ad8\u7684\u6e29\u5ea6\u4e0b\uff0c\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd\u53ef\u80fd\u4f1a\u53d7\u5230\u6291\u5236\u3002\u6839\u636e\u50ac\u5316\u6d3b\u6027\u6d4b\u8bd5\u7ed3\u679c\uff0c9727\u50ac\u5316\u5242\u7684\u4f73\u4f7f\u7528\u6e29\u5ea6\u8303\u56f4\u4e3a75\u00b0C\u81f3100\u00b0C\uff0c\u5728\u6b64\u6e29\u5ea6\u533a\u95f4\u5185\uff0c\u50ac\u5316\u5242\u8868\u73b0\u51fa\u9ad8\u7684\u50ac\u5316\u6548\u7387\u548c\u4f73\u7684\u4ea7\u54c1\u6027\u80fd\u3002\u7136\u800c\uff0c\u5728125\u00b0C\u65f6\uff0c\u867d\u7136\u53cd\u5e94\u65f6\u95f4\u77ed\uff0c\u4f46\u8f6c\u5316\u7387\u7565\u6709\u4e0b\u964d\uff0c\u4ea7\u7269\u786c\u5ea6\u4e5f\u8d8b\u4e8e\u9971\u548c\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u8fc7\u9ad8\u7684\u6e29\u5ea6\u5bfc\u81f4\u50ac\u5316\u5242\u90e8\u5206\u5931\u6d3b\u6240\u81f4\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u6e29\u5ea6\u4f9d\u8d56\u6027<\/strong>\uff1a9727\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u4e0e\u5176\u4f7f\u7528\u6e29\u5ea6\u5bc6\u5207\u76f8\u5173\u3002\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\uff0c\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u8f83\u4f4e\uff0c\u53cd\u5e94\u65f6\u95f4\u8f83\u957f\uff1b\u800c\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\uff0c\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u867d\u7136\u8f83\u9ad8\uff0c\u4f46\u53ef\u80fd\u5b58\u5728\u5931\u6d3b\u7684\u98ce\u9669\u3002\u56e0\u6b64\uff0c\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u5e94\u6839\u636e\u5177\u4f53\u7684\u5de5\u827a\u8981\u6c42\u9009\u62e9\u5408\u9002\u7684\u6e29\u5ea6\u8303\u56f4\uff0c\u4ee5\u786e\u4fdd\u50ac\u5316\u5242\u7684\u4f73\u6027\u80fd\u3002<\/p>\n<\/li>\n<\/ol>\n<h3>\u5c55\u671b<\/h3>\n<p>\u5c3d\u7ba197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href=\"https:\/\/www.cyclohexylamine.net\/low-odor-amine-catalyst-pt305-reactive-amine-catalyst-pt305\/\">https:\/\/www.cyclohexylamine.net\/low-odor-amine-catalyst-pt305-reactive-amine-catalyst-pt305\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/fentacat-10-catalyst-cas100-42-5-solvay\/\">https:\/\/www.bdmaee.net\/fentacat-10-catalyst-cas100-42-5-solvay\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/156\">https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/156<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.cyclohexylamine.net\/dabco-ne300-nnn-trimethyl-n-3-aminopropyl-bisaminoethyl-ether\/\">https:\/\/www.cyclohexylamine.net\/dabco-ne300-nnn-trimethyl-n-3-aminopropyl-bisaminoethyl-ether\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.cyclohexylamine.net\/dabco-xd-104-dabco-tertiary-amine-catalyst\/\">https:\/\/www.cyclohexylamine.net\/dabco-xd-104-dabco-tertiary-amine-catalyst\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/lupragen-n302-catalyst-basf\/\">https:\/\/www.bdmaee.net\/lupragen-n302-catalyst-basf\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/38910\">https:\/\/www.newtopchem.com\/archives\/38910<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/wp-content\/uploads\/2019\/10\/NEWTOP2.jpg\">https:\/\/www.bdmaee.net\/wp-content\/uploads\/2019\/10\/NEWTOP2.jpg<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/81\">https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/81<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/846\">https:\/\/www.newtopchem.com\/archives\/846<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5f15\u8a00 \u805a\u6c28\u916f\uff08Polyurethane, PU\uff09\u662f\u4e00\u79cd\u7531\u5f02\u6c30\u9178\u916f\u548c\u591a\u5143\u9187\u53cd\u5e94\u751f\u6210\u7684\u9ad8\u5206\u5b50\u6750\u6599\uff0c\u56e0\u5176\u4f18\u5f02\u7684\u7269\u7406\u6027\u80fd\u548c\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u5728\u4f17\u591a\u9886\u57df\u5f97\u5230\u4e86\u5e7f\u6cdb\u5e94\u7528\u3002\u4ece\u5efa\u7b51\u4fdd\u6e29\u3001\u6c7d\u8f66\u5236\u9020\u5230\u5bb6\u5177\u3001\u978b\u6750\u7b49\uff0c\u805a\u6c28\u916f\u7684\u8eab\u5f71\u65e0\u5904\u4e0d\u5728\u3002\u7136\u800c\uff0c\u805a\u6c28\u916f\u7684\u5408\u6210\u8fc7\u7a0b\u590d\u6742\uff0c\u5c24\u5176\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\uff0c\u50ac\u5316\u5242\u7684\u9009\u62e9\u81f3\u5173\u91cd\u8981\u3002\u50ac\u5316\u5242\u4e0d\u4ec5\u5f71\u54cd\u53cd\u5e94\u901f\u7387\uff0c\u8fd8\u51b3\u5b9a\u4e86\u7ec8\u4ea7\u54c1\u7684\u6027 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[2272],"_links":{"self":[{"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/posts\/6249"}],"collection":[{"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/comments?post=6249"}],"version-history":[{"count":0,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/posts\/6249\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/media?parent=6249"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/categories?post=6249"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/tags?post=6249"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}