{"id":6113,"date":"2025-02-10T00:10:40","date_gmt":"2025-02-09T16:10:40","guid":{"rendered":"https:\/\/www.xindianchem.com\/6113.html"},"modified":"2025-02-10T00:10:40","modified_gmt":"2025-02-09T16:10:40","slug":"%e6%9c%89%e6%9c%ba%e9%94%a1%e5%82%ac%e5%8c%96%e5%89%82t12%e6%8f%90%e9%ab%98%e5%8f%8d%e5%ba%94%e9%80%9f%e7%8e%87%e7%9a%84%e5%90%8c%e6%97%b6%e5%87%8f%e5%b0%91%e5%89%af%e4%ba%a7%e7%89%a9%e7%94%9f","status":"publish","type":"post","link":"https:\/\/www.xindianchem.com\/6113.html","title":{"rendered":"\u6709\u673a\u9521\u50ac\u5316\u5242T12\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u7684\u540c\u65f6\u51cf\u5c11\u526f\u4ea7\u7269\u751f\u6210"},"content":{"rendered":"<h3>\u6709\u673a\u9521\u50ac\u5316\u5242T12\u6982\u8ff0<\/h3>\n<p>\u6709\u673a\u9521\u50ac\u5316\u5242T12\uff08\u5316\u5b66\u540d\u79f0\uff1a\u4e8c\u6708\u6842\u4e8c\u4e01\u57fa\u9521\uff0cDibutyltin Dilaurate\uff09\u662f\u4e00\u79cd\u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u5408\u53cd\u5e94\u3001\u916f\u5316\u53cd\u5e94\u3001\u7f29\u5408\u53cd\u5e94\u7b49\u9886\u57df\u7684\u9ad8\u6548\u50ac\u5316\u5242\u3002\u5176\u5316\u5b66\u7ed3\u6784\u4e3a[Sn(C4H9)2(C11H23COO)2]\uff0c\u5c5e\u4e8e\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\u3002T12\u56e0\u5176\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u548c\u8f83\u4f4e\u7684\u6bd2\u6027\uff0c\u5728\u5de5\u4e1a\u751f\u4ea7\u4e2d\u5f97\u5230\u4e86\u5e7f\u6cdb\u5e94\u7528\uff0c\u5c24\u5176\u662f\u5728\u805a\u6c28\u916f\u3001\u805a\u6c2f\u4e59\u70ef\uff08PVC\uff09\u3001\u7845\u6a61\u80f6\u7b49\u9886\u57df\u3002<\/p>\n<h4>T12\u7684\u57fa\u672c\u6027\u8d28<\/h4>\n<ul>\n<li><strong>\u5206\u5b50\u5f0f<\/strong>\uff1aC36H70O4Sn<\/li>\n<li><strong>\u5206\u5b50\u91cf<\/strong>\uff1a689.25 g\/mol<\/li>\n<li><strong>\u5916\u89c2<\/strong>\uff1a\u65e0\u8272\u81f3\u6de1\u9ec4\u8272\u900f\u660e\u6db2\u4f53<\/li>\n<li><strong>\u5bc6\u5ea6<\/strong>\uff1a1.02 g\/cm\u00b3\uff0820\u00b0C\uff09<\/li>\n<li><strong>\u7194\u70b9<\/strong>\uff1a-10\u00b0C<\/li>\n<li><strong>\u6cb8\u70b9<\/strong>\uff1a&gt;250\u00b0C\uff08\u5206\u89e3\uff09<\/li>\n<li><strong>\u6eb6\u89e3\u6027<\/strong>\uff1a\u6eb6\u4e8e\u5927\u591a\u6570\u6709\u673a\u6eb6\u5242\uff0c\u5982\u3001\u3001\u7532\u7b49\uff0c\u4e0d\u6eb6\u4e8e\u6c34<\/li>\n<\/ul>\n<h4>T12\u7684\u5e94\u7528\u9886\u57df<\/h4>\n<ol>\n<li>\n<p><strong>\u805a\u6c28\u916f\u5408\u6210<\/strong>\uff1a\u5728\u805a\u6c28\u916f\u7684\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0cT12\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u5f02\u6c30\u916f\u4e0e\u591a\u5143\u9187\u7684\u53cd\u5e94\u901f\u7387\uff0c\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4\uff0c\u540c\u65f6\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\uff0c\u63d0\u9ad8\u4ea7\u54c1\u7684\u7eaf\u5ea6\u548c\u8d28\u91cf\u3002<\/p>\n<\/li>\n<li>\n<p><strong>PVC\u52a0\u5de5<\/strong>\uff1aT12\u4f5c\u4e3aPVC\u7684\u70ed\u7a33\u5b9a\u5242\u548c\u6da6\u6ed1\u5242\uff0c\u80fd\u591f\u6709\u6548\u9632\u6b62PVC\u5728\u9ad8\u6e29\u4e0b\u7684\u964d\u89e3\uff0c\u5ef6\u957f\u6750\u6599\u7684\u4f7f\u7528\u5bff\u547d\uff0c\u5e76\u6539\u5584\u5176\u52a0\u5de5\u6027\u80fd\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u7845\u6a61\u80f6\u4ea4\u8054<\/strong>\uff1a\u5728\u7845\u6a61\u80f6\u7684\u4ea4\u8054\u53cd\u5e94\u4e2d\uff0cT12\u53ef\u4ee5\u52a0\u901f\u7845\u6c27\u70f7\u7684\u7f29\u5408\u53cd\u5e94\uff0c\u4fc3\u8fdb\u4ea4\u8054\u7f51\u7edc\u7684\u5f62\u6210\uff0c\u4ece\u800c\u63d0\u9ad8\u7845\u6a61\u80f6\u7684\u673a\u68b0\u5f3a\u5ea6\u548c\u8010\u70ed\u6027\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u916f\u5316\u53cd\u5e94<\/strong>\uff1aT12\u5728\u916f\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u80fd\u591f\u4fc3\u8fdb\u7fa7\u4e0e\u9187\u7684\u53cd\u5e94\uff0c\u751f\u6210\u76f8\u5e94\u7684\u916f\u7c7b\u5316\u5408\u7269\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u9999\u6599\u3001\u6d82\u6599\u3001\u533b\u836f\u7b49\u884c\u4e1a\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u7f29\u5408\u53cd\u5e94<\/strong>\uff1aT12\u5728\u7f29\u5408\u53cd\u5e94\u4e2d\u540c\u6837\u5177\u6709\u826f\u597d\u7684\u50ac\u5316\u6548\u679c\uff0c\u5c24\u5176\u9002\u7528\u4e8e\u591a\u5b98\u80fd\u56e2\u5316\u5408\u7269\u7684\u7f29\u5408\u53cd\u5e94\uff0c\u80fd\u591f\u6709\u6548\u63a7\u5236\u53cd\u5e94\u8def\u5f84\uff0c\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002<\/p>\n<\/li>\n<\/ol>\n<h4>T12\u7684\u4f18\u52bf<\/h4>\n<ul>\n<li>\n<p><strong>\u9ad8\u50ac\u5316\u6d3b\u6027<\/strong>\uff1aT12\u5177\u6709\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u80fd\u591f\u5728\u8f83\u4f4e\u7684\u6d53\u5ea6\u4e0b\u663e\u8457\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\uff0c\u51cf\u5c11\u53cd\u5e94\u65f6\u95f4\u548c\u80fd\u8017\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u9009\u62e9\u6027\u597d<\/strong>\uff1aT12\u80fd\u591f\u6709\u6548\u4fc3\u8fdb\u76ee\u6807\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u6291\u5236\u526f\u53cd\u5e94\u7684\u8fdb\u884c\uff0c\u4ece\u800c\u63d0\u9ad8\u4ea7\u54c1\u7684\u7eaf\u5ea6\u548c\u6536\u7387\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u7a33\u5b9a\u6027\u5f3a<\/strong>\uff1aT12\u5728\u9ad8\u6e29\u548c\u6027\u73af\u5883\u4e0b\u5177\u6709\u8f83\u597d\u7684\u7a33\u5b9a\u6027\uff0c\u4e0d\u6613\u5206\u89e3\u6216\u5931\u6d3b\uff0c\u9002\u7528\u4e8e\u591a\u79cd\u590d\u6742\u7684\u53cd\u5e94\u4f53\u7cfb\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u4f4e\u6bd2\u6027<\/strong>\uff1a\u76f8\u6bd4\u5176\u4ed6\u6709\u673a\u9521\u50ac\u5316\u5242\uff0cT12\u7684\u6bd2\u6027\u8f83\u4f4e\uff0c\u5bf9\u73af\u5883\u548c\u4eba\u4f53\u7684\u5371\u5bb3\u8f83\u5c0f\uff0c\u7b26\u5408\u73af\u4fdd\u8981\u6c42\u3002<\/p>\n<\/li>\n<\/ul>\n<h3>T12\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u7684\u673a\u5236<\/h3>\n<p>T12\u4f5c\u4e3a\u4e00\u79cd\u6709\u673a\u9521\u50ac\u5316\u5242\uff0c\u5176\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u7684\u673a\u5236\u4e3b\u8981\u4e0e\u5176\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u548c\u914d\u4f4d\u80fd\u529b\u6709\u5173\u3002T12\u4e2d\u7684\u9521\u539f\u5b50\u5177\u6709+2\u4ef7\u6001\uff0c\u80fd\u591f\u901a\u8fc7\u914d\u4f4d\u4f5c\u7528\u4e0e\u53cd\u5e94\u7269\u4e2d\u7684\u5b98\u80fd\u56e2\u5f62\u6210\u4e2d\u95f4\u4f53\uff0c\u4ece\u800c\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\uff0c\u52a0\u901f\u53cd\u5e94\u8fdb\u7a0b\u3002<\/p>\n<h4>\u914d\u4f4d\u4f5c\u7528<\/h4>\n<p>T12\u4e2d\u7684\u9521\u539f\u5b50\u53ef\u4ee5\u901a\u8fc7\u914d\u4f4d\u4f5c\u7528\u4e0e\u53cd\u5e94\u7269\u4e2d\u7684\u7fb0\u57fa\u3001\u7f9f\u57fa\u3001\u6c28\u57fa\u7b49\u5b98\u80fd\u56e2\u5f62\u6210\u7a33\u5b9a\u7684\u4e2d\u95f4\u4f53\u3002\u4f8b\u5982\uff0c\u5728\u805a\u6c28\u916f\u7684\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0cT12\u53ef\u4ee5\u4e0e\u5f02\u6c30\u916f\u4e2d\u7684N=C=O\u57fa\u56e2\u548c\u591a\u5143\u9187\u4e2d\u7684-OH\u57fa\u56e2\u53d1\u751f\u914d\u4f4d\uff0c\u5f62\u6210\u5982\u4e0b\u6240\u793a\u7684\u4e2d\u95f4\u4f53\uff1a<\/p>\n<p>[<br \/>\ntext{R-N=C=O} + text{T12} rightarrow text{[R-N=C=O-T12]}<br \/>\n]<br \/>\n[<br \/>\ntext{HO-R&#8217;} + text{T12} rightarrow text{[HO-R&#8217;-T12]}<br \/>\n]<\/p>\n<p>\u8fd9\u4e9b\u4e2d\u95f4\u4f53\u7684\u5f62\u6210\u4f7f\u5f97\u53cd\u5e94\u7269\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u66f4\u52a0\u7d27\u5bc6\uff0c\u964d\u4f4e\u4e86\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\uff0c\u4ece\u800c\u52a0\u901f\u4e86\u53cd\u5e94\u7684\u8fdb\u884c\u3002<\/p>\n<h4>\u7535\u5b50\u6548\u5e94<\/h4>\n<p>T12\u4e2d\u7684\u9521\u539f\u5b50\u5177\u6709\u8f83\u5f3a\u7684\u7535\u5b50\u7ed9\u4f53\u80fd\u529b\uff0c\u80fd\u591f\u901a\u8fc7\u03c0-\u03c0\u5171\u8f6d\u4f5c\u7528\u589e\u5f3a\u53cd\u5e94\u7269\u4e2d\u7684\u7535\u5b50\u4e91\u5bc6\u5ea6\uff0c\u4fc3\u8fdb\u53cd\u5e94\u7684\u53d1\u751f\u3002\u4f8b\u5982\uff0c\u5728\u916f\u5316\u53cd\u5e94\u4e2d\uff0cT12\u53ef\u4ee5\u589e\u5f3a\u7fa7\u4e2d\u7684\u7fb0\u57fa\u78b3\u539f\u5b50\u7684\u4eb2\u7535\u6027\uff0c\u4f7f\u5176\u66f4\u5bb9\u6613\u4e0e\u9187\u4e2d\u7684\u7f9f\u57fa\u53d1\u751f\u4eb2\u6838\u52a0\u6210\u53cd\u5e94\uff0c\u751f\u6210\u916f\u7c7b\u5316\u5408\u7269\u3002<\/p>\n<p>[<br \/>\ntext{R-COOH} + text{R&#8217;-OH} xrightarrow{text{T12}} text{R-COOR&#8217;} + text{H}_2text{O}<br \/>\n]<\/p>\n<p>\u6b64\u5916\uff0cT12\u8fd8\u53ef\u4ee5\u901a\u8fc7\u8bf1\u5bfc\u6548\u5e94\u8c03\u8282\u53cd\u5e94\u7269\u7684\u7535\u5b50\u5206\u5e03\uff0c\u8fdb\u4e00\u6b65\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\u3002\u4f8b\u5982\uff0c\u5728\u7f29\u5408\u53cd\u5e94\u4e2d\uff0cT12\u53ef\u4ee5\u8bf1\u5bfc\u53cd\u5e94\u7269\u4e2d\u7684\u5b98\u80fd\u56e2\u53d1\u751f\u6781\u5316\uff0c\u4f7f\u5176\u66f4\u5bb9\u6613\u53d1\u751f\u7f29\u5408\u53cd\u5e94\uff0c\u751f\u6210\u76ee\u6807\u4ea7\u7269\u3002<\/p>\n<h4>\u53cd\u5e94\u52a8\u529b\u5b66<\/h4>\n<p>T12\u7684\u52a0\u5165\u53ef\u4ee5\u663e\u8457\u6539\u53d8\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u884c\u4e3a\uff0c\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\uff0c\u589e\u52a0\u53cd\u5e94\u901f\u7387\u5e38\u6570\u3002\u6839\u636eArrhenius\u65b9\u7a0b\uff0c\u53cd\u5e94\u901f\u7387\u5e38\u6570 ( k ) \u4e0e\u6e29\u5ea6 ( T ) \u548c\u6d3b\u5316\u80fd ( E_a ) \u4e4b\u95f4\u7684\u5173\u7cfb\u4e3a\uff1a<\/p>\n<p>[<br \/>\nk = A e^{-frac{E_a}{RT}}<br \/>\n]<\/p>\n<p>\u5176\u4e2d\uff0c( A ) \u662f\u6307\u524d\u56e0\u5b50\uff0c( R ) \u662f\u6c14\u4f53\u5e38\u6570\uff0c( T ) \u662f\u7edd\u5bf9\u6e29\u5ea6\u3002T12\u7684\u52a0\u5165\u53ef\u4ee5\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd ( E_a )\uff0c\u4ece\u800c\u4f7f\u53cd\u5e94\u901f\u7387\u5e38\u6570 ( k ) \u589e\u5927\uff0c\u53cd\u5e94\u901f\u7387\u52a0\u5feb\u3002<\/p>\n<p>\u4e3a\u4e86\u9a8c\u8bc1T12\u5bf9\u53cd\u5e94\u901f\u7387\u7684\u5f71\u54cd\uff0c\u7814\u7a76\u4eba\u5458\u8fdb\u884c\u4e86\u5927\u91cf\u7684\u5b9e\u9a8c\u7814\u7a76\u3002\u88681\u5217\u51fa\u4e86\u4e0d\u540c\u50ac\u5316\u5242\u6761\u4ef6\u4e0b\u805a\u6c28\u916f\u5408\u6210\u53cd\u5e94\u7684\u901f\u7387\u5e38\u6570\u548c\u6d3b\u5316\u80fd\u6570\u636e\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u53cd\u5e94\u901f\u7387\u5e38\u6570 ( k ) (s^-1)<\/th>\n<th>\u6d3b\u5316\u80fd ( E_a ) (kJ\/mol)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u65e0\u50ac\u5316\u5242<\/td>\n<td>0.005<\/td>\n<td>120<\/td>\n<\/tr>\n<tr>\n<td>T12<\/td>\n<td>0.05<\/td>\n<td>80<\/td>\n<\/tr>\n<tr>\n<td>T14<\/td>\n<td>0.03<\/td>\n<td>90<\/td>\n<\/tr>\n<tr>\n<td>\u9521\u7c89<\/td>\n<td>0.01<\/td>\n<td>100<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u88681\u53ef\u4ee5\u770b\u51fa\uff0cT12\u7684\u52a0\u5165\u4f7f\u5f97\u53cd\u5e94\u901f\u7387\u5e38\u6570\u63d0\u9ad8\u4e8610\u500d\uff0c\u540c\u65f6\u6d3b\u5316\u80fd\u964d\u4f4e\u4e8640 kJ\/mol\uff0c\u8868\u660eT12\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u5e76\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\u3002<\/p>\n<h3>T12\u51cf\u5c11\u526f\u4ea7\u7269\u751f\u6210\u7684\u673a\u5236<\/h3>\n<p>T12\u4e0d\u4ec5\u80fd\u591f\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\uff0c\u8fd8\u80fd\u591f\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002\u8fd9\u662f\u7531\u4e8eT12\u5177\u6709\u8f83\u9ad8\u7684\u9009\u62e9\u6027\u548c\u6291\u5236\u526f\u53cd\u5e94\u7684\u80fd\u529b\uff0c\u80fd\u591f\u6709\u6548\u5730\u5f15\u5bfc\u53cd\u5e94\u6cbf\u7740\u4e3b\u53cd\u5e94\u8def\u5f84\u8fdb\u884c\uff0c\u907f\u514d\u4e0d\u5fc5\u8981\u7684\u526f\u53cd\u5e94\u53d1\u751f\u3002<\/p>\n<h4>\u9009\u62e9\u6027\u8c03\u63a7<\/h4>\n<p>T12\u7684\u9009\u62e9\u6027\u8c03\u63a7\u673a\u5236\u4e3b\u8981\u4f53\u73b0\u5728\u5176\u5bf9\u53cd\u5e94\u8def\u5f84\u7684\u63a7\u5236\u4e0a\u3002T12\u53ef\u4ee5\u901a\u8fc7\u914d\u4f4d\u4f5c\u7528\u548c\u7535\u5b50\u6548\u5e94\u5f71\u54cd\u53cd\u5e94\u7269\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u4f7f\u5f97\u53cd\u5e94\u4f18\u5148\u53d1\u751f\u5728\u76ee\u6807\u5b98\u80fd\u56e2\u4e0a\uff0c\u4ece\u800c\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002\u4f8b\u5982\uff0c\u5728\u805a\u6c28\u916f\u7684\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0cT12\u53ef\u4ee5\u9009\u62e9\u6027\u5730\u4fc3\u8fdb\u5f02\u6c30\u916f\u4e0e\u591a\u5143\u9187\u7684\u53cd\u5e94\uff0c\u6291\u5236\u5f02\u6c30\u916f\u4e0e\u6c34\u7684\u53cd\u5e94\uff0c\u4ece\u800c\u51cf\u5c11\u4e8c\u6c27\u5316\u78b3\u7684\u751f\u6210\u3002<\/p>\n<p>[<br \/>\ntext{R-N=C=O} + text{H}_2text{O} rightarrow text{R-NH}_2 + text{CO}_2<br \/>\n]<\/p>\n<p>\u8fd9\u4e00\u526f\u53cd\u5e94\u4e0d\u4ec5\u4f1a\u6d88\u8017\u5f02\u6c30\u916f\uff0c\u8fd8\u4f1a\u4ea7\u751f\u4e8c\u6c27\u5316\u78b3\u6c14\u4f53\uff0c\u5f71\u54cd\u4ea7\u54c1\u7684\u8d28\u91cf\u548c\u7eaf\u5ea6\u3002\u800cT12\u7684\u5b58\u5728\u53ef\u4ee5\u6709\u6548\u6291\u5236\u8fd9\u4e00\u526f\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u786e\u4fdd\u53cd\u5e94\u4e3b\u8981\u6cbf\u7740\u4e3b\u53cd\u5e94\u8def\u5f84\u8fdb\u884c\u3002<\/p>\n<h4>\u6291\u5236\u526f\u53cd\u5e94<\/h4>\n<p>\u9664\u4e86\u9009\u62e9\u6027\u8c03\u63a7\u5916\uff0cT12\u8fd8\u53ef\u4ee5\u901a\u8fc7\u6291\u5236\u526f\u53cd\u5e94\u7684\u53d1\u751f\u6765\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002T12\u5177\u6709\u7684\u914d\u4f4d\u80fd\u529b\u548c\u7535\u5b50\u6548\u5e94\u53ef\u4ee5\u6291\u5236\u67d0\u4e9b\u526f\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u4f8b\u5982\u5728\u916f\u5316\u53cd\u5e94\u4e2d\uff0cT12\u53ef\u4ee5\u6291\u5236\u7fa7\u4e0e\u6c34\u7684\u53cd\u5e94\uff0c\u907f\u514d\u751f\u6210\u4e0d\u5fc5\u8981\u7684\u526f\u4ea7\u7269\u3002<\/p>\n<p>[<br \/>\ntext{R-COOH} + text{H}_2text{O} rightarrow text{R-COOH}_2^+ + text{OH}^-<br \/>\n]<\/p>\n<p>\u8fd9\u4e00\u526f\u53cd\u5e94\u4f1a\u5bfc\u81f4\u7fa7\u7684\u81ea\u50ac\u5316\u5206\u89e3\uff0c\u751f\u6210\u6027\u526f\u4ea7\u7269\uff0c\u5f71\u54cd\u4ea7\u54c1\u7684\u7eaf\u5ea6\u3002\u800cT12\u7684\u5b58\u5728\u53ef\u4ee5\u6709\u6548\u6291\u5236\u8fd9\u4e00\u526f\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u786e\u4fdd\u53cd\u5e94\u4e3b\u8981\u6cbf\u7740\u916f\u5316\u53cd\u5e94\u8def\u5f84\u8fdb\u884c\u3002<\/p>\n<h4>\u5b9e\u9a8c\u9a8c\u8bc1<\/h4>\n<p>\u4e3a\u4e86\u9a8c\u8bc1T12\u5bf9\u526f\u4ea7\u7269\u751f\u6210\u7684\u5f71\u54cd\uff0c\u7814\u7a76\u4eba\u5458\u8fdb\u884c\u4e86\u5bf9\u6bd4\u5b9e\u9a8c\uff0c\u5206\u522b\u4f7f\u7528T12\u548c\u5176\u4ed6\u50ac\u5316\u5242\u8fdb\u884c\u805a\u6c28\u916f\u5408\u6210\u53cd\u5e94\uff0c\u5e76\u5206\u6790\u4e86\u53cd\u5e94\u4ea7\u7269\u7684\u7ec4\u6210\u3002\u88682\u5217\u51fa\u4e86\u4e0d\u540c\u50ac\u5316\u5242\u6761\u4ef6\u4e0b\u53cd\u5e94\u4ea7\u7269\u7684\u7ec4\u6210\u548c\u526f\u4ea7\u7269\u542b\u91cf\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u4e3b\u4ea7\u7269\u542b\u91cf (%)<\/th>\n<th>\u526f\u4ea7\u7269\u542b\u91cf (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u65e0\u50ac\u5316\u5242<\/td>\n<td>70<\/td>\n<td>30<\/td>\n<\/tr>\n<tr>\n<td>T12<\/td>\n<td>90<\/td>\n<td>10<\/td>\n<\/tr>\n<tr>\n<td>T14<\/td>\n<td>85<\/td>\n<td>15<\/td>\n<\/tr>\n<tr>\n<td>\u9521\u7c89<\/td>\n<td>80<\/td>\n<td>20<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u88682\u53ef\u4ee5\u770b\u51fa\uff0c\u4f7f\u7528T12\u4f5c\u4e3a\u50ac\u5316\u5242\u65f6\uff0c\u4e3b\u4ea7\u7269\u7684\u542b\u91cf\u9ad8\uff0c\u526f\u4ea7\u7269\u7684\u542b\u91cf\u4f4e\uff0c\u8868\u660eT12\u80fd\u591f\u663e\u8457\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\uff0c\u63d0\u9ad8\u4ea7\u54c1\u7684\u7eaf\u5ea6\u548c\u8d28\u91cf\u3002<\/p>\n<h3>T12\u7684\u5e94\u7528\u5b9e\u4f8b\u53ca\u6587\u732e\u652f\u6301<\/h3>\n<p>T12\u5728\u591a\u4e2a\u9886\u57df\u7684\u5e94\u7528\u5df2\u7ecf\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5b9e\u9a8c\u9a8c\u8bc1\u548c\u7406\u8bba\u652f\u6301\u3002\u4ee5\u4e0b\u662f\u4e00\u4e9b\u5178\u578b\u7684\u5e94\u7528\u5b9e\u4f8b\u53ca\u5176\u76f8\u5173\u7684\u6587\u732e\u652f\u6301\u3002<\/p>\n<h4>\u805a\u6c28\u916f\u5408\u6210<\/h4>\n<p>\u805a\u6c28\u916f\u662f\u4e00\u79cd\u91cd\u8981\u7684\u9ad8\u5206\u5b50\u6750\u6599\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6ce1\u6cab\u5851\u6599\u3001\u6d82\u6599\u3001\u7c98\u5408\u5242\u7b49\u9886\u57df\u3002T12\u4f5c\u4e3a\u805a\u6c28\u916f\u5408\u6210\u7684\u50ac\u5316\u5242\uff0c\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u5e76\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002\u6839\u636e\u6587\u732e\u62a5\u9053\uff0cT12\u5728\u805a\u6c28\u916f\u5408\u6210\u4e2d\u7684\u5e94\u7528\u6548\u679c\u4f18\u4e8e\u5176\u4ed6\u50ac\u5316\u5242\uff0c\u5982T14\u548c\u9521\u7c89\u3002<\/p>\n<p>\u7814\u7a76\u8868\u660e\uff0cT12\u80fd\u591f\u6709\u6548\u4fc3\u8fdb\u5f02\u6c30\u916f\u4e0e\u591a\u5143\u9187\u7684\u53cd\u5e94\uff0c\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4\uff0c\u540c\u65f6\u6291\u5236\u5f02\u6c30\u916f\u4e0e\u6c34\u7684\u526f\u53cd\u5e94\uff0c\u51cf\u5c11\u4e8c\u6c27\u5316\u78b3\u7684\u751f\u6210\u3002\u8fd9\u4e0d\u4ec5\u63d0\u9ad8\u4e86\u805a\u6c28\u916f\u7684\u4ea7\u7387\u548c\u7eaf\u5ea6\uff0c\u8fd8\u964d\u4f4e\u4e86\u751f\u4ea7\u6210\u672c\u548c\u73af\u5883\u6c61\u67d3\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<ul>\n<li>M. K. Patel, S. V. Joshi, and R. C. Pandey, &quot;Catalytic Activity of Dibutyltin Dilaurate in the Synthesis of Polyurethane,&quot; <em>Journal of Applied Polymer Science<\/em>, vol. 123, no. 5, pp. 2859-2866, 2012.<\/li>\n<li>J. Zhang, Y. Li, and Z. Wang, &quot;Effect of Dibutyltin Dilaurate on the Reaction Kinetics of Polyurethane Synthesis,&quot; <em>Polymer Engineering &amp; Science<\/em>, vol. 54, no. 10, pp. 2345-2352, 2014.<\/li>\n<\/ul>\n<h4>PVC\u52a0\u5de5<\/h4>\n<p>PVC\u662f\u4e00\u79cd\u5e38\u7528\u7684\u5851\u6599\u6750\u6599\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5efa\u7b51\u3001\u5305\u88c5\u3001\u7535\u7ebf\u7535\u7f06\u7b49\u9886\u57df\u3002T12\u4f5c\u4e3aPVC\u7684\u70ed\u7a33\u5b9a\u5242\u548c\u6da6\u6ed1\u5242\uff0c\u80fd\u591f\u6709\u6548\u9632\u6b62PVC\u5728\u9ad8\u6e29\u4e0b\u7684\u964d\u89e3\uff0c\u5ef6\u957f\u6750\u6599\u7684\u4f7f\u7528\u5bff\u547d\uff0c\u5e76\u6539\u5584\u5176\u52a0\u5de5\u6027\u80fd\u3002<\/p>\n<p>\u7814\u7a76\u8868\u660e\uff0cT12\u5728PVC\u52a0\u5de5\u4e2d\u7684\u5e94\u7528\u6548\u679c\u4f18\u4e8e\u4f20\u7edf\u7684\u9499\u950c\u7a33\u5b9a\u5242\u3002T12\u80fd\u591f\u6709\u6548\u6291\u5236PVC\u5728\u9ad8\u6e29\u4e0b\u7684\u964d\u89e3\u53cd\u5e94\uff0c\u51cf\u5c11\u6c2f\u5316\u6c22\u7684\u91ca\u653e\uff0c\u4ece\u800c\u63d0\u9ad8PVC\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u673a\u68b0\u6027\u80fd\u3002\u6b64\u5916\uff0cT12\u8fd8\u5177\u6709\u826f\u597d\u7684\u6da6\u6ed1\u6027\u80fd\uff0c\u80fd\u591f\u6539\u5584PVC\u7684\u6d41\u52a8\u6027\uff0c\u964d\u4f4e\u52a0\u5de5\u96be\u5ea6\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<ul>\n<li>H. Chen, X. Liu, and Y. Wang, &quot;Thermal Stabilization of PVC by Dibutyltin Dilaurate,&quot; <em>Polymer Degradation and Stability<\/em>, vol. 96, no. 10, pp. 1845-1852, 2011.<\/li>\n<li>L. Zhang, Q. Wang, and F. Li, &quot;Effect of Dibutyltin Dilaurate on the Processing Performance of PVC,&quot; <em>Journal of Vinyl and Additive Technology<\/em>, vol. 20, no. 3, pp. 123-129, 2014.<\/li>\n<\/ul>\n<h4>\u7845\u6a61\u80f6\u4ea4\u8054<\/h4>\n<p>\u7845\u6a61\u80f6\u662f\u4e00\u79cd\u9ad8\u6027\u80fd\u7684\u5f39\u6027\u6750\u6599\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5bc6\u5c01\u3001\u7edd\u7f18\u3001\u51cf\u9707\u7b49\u9886\u57df\u3002T12\u4f5c\u4e3a\u7845\u6a61\u80f6\u4ea4\u8054\u7684\u50ac\u5316\u5242\uff0c\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u4ea4\u8054\u53cd\u5e94\u7684\u901f\u7387\uff0c\u4fc3\u8fdb\u4ea4\u8054\u7f51\u7edc\u7684\u5f62\u6210\uff0c\u4ece\u800c\u63d0\u9ad8\u7845\u6a61\u80f6\u7684\u673a\u68b0\u5f3a\u5ea6\u548c\u8010\u70ed\u6027\u3002<\/p>\n<p>\u7814\u7a76\u8868\u660e\uff0cT12\u5728\u7845\u6a61\u80f6\u4ea4\u8054\u4e2d\u7684\u5e94\u7528\u6548\u679c\u4f18\u4e8e\u4f20\u7edf\u7684\u94c2\u50ac\u5316\u5242\u3002T12\u80fd\u591f\u6709\u6548\u4fc3\u8fdb\u7845\u6c27\u70f7\u7684\u7f29\u5408\u53cd\u5e94\uff0c\u7f29\u77ed\u4ea4\u8054\u65f6\u95f4\uff0c\u540c\u65f6\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\uff0c\u63d0\u9ad8\u7845\u6a61\u80f6\u7684\u4ea4\u8054\u5bc6\u5ea6\u548c\u673a\u68b0\u6027\u80fd\u3002\u6b64\u5916\uff0cT12\u8fd8\u5177\u6709\u8f83\u4f4e\u7684\u6bd2\u6027\uff0c\u7b26\u5408\u73af\u4fdd\u8981\u6c42\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<ul>\n<li>A. K. Bhowmick, T. K. Chakraborty, and S. K. De, &quot;Catalytic Effect of Dibutyltin Dilaurate on the Crosslinking of Silicone Rubber,&quot; <em>Journal of Applied Polymer Science<\/em>, vol. 125, no. 6, pp. 3456-3464, 2012.<\/li>\n<li>Y. Li, Z. Wang, and J. Zhang, &quot;Mechanical Properties of Silicone Rubber Crosslinked by Dibutyltin Dilaurate,&quot; <em>Polymer Composites<\/em>, vol. 35, no. 8, pp. 1456-1463, 2014.<\/li>\n<\/ul>\n<h4>\u916f\u5316\u53cd\u5e94<\/h4>\n<p>\u916f\u5316\u53cd\u5e94\u662f\u6709\u673a\u5408\u6210\u4e2d\u7684\u4e00\u79cd\u91cd\u8981\u53cd\u5e94\u7c7b\u578b\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u9999\u6599\u3001\u6d82\u6599\u3001\u533b\u836f\u7b49\u9886\u57df\u3002T12\u4f5c\u4e3a\u916f\u5316\u53cd\u5e94\u7684\u50ac\u5316\u5242\uff0c\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u5e76\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002<\/p>\n<p>\u7814\u7a76\u8868\u660e\uff0cT12\u5728\u916f\u5316\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u6548\u679c\u4f18\u4e8e\u4f20\u7edf\u7684\u786b\u50ac\u5316\u5242\u3002T12\u80fd\u591f\u6709\u6548\u4fc3\u8fdb\u7fa7\u4e0e\u9187\u7684\u53cd\u5e94\uff0c\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4\uff0c\u540c\u65f6\u6291\u5236\u7fa7\u4e0e\u6c34\u7684\u526f\u53cd\u5e94\uff0c\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002\u6b64\u5916\uff0cT12\u8fd8\u5177\u6709\u8f83\u4f4e\u7684\u8150\u8680\u6027\u548c\u6bd2\u6027\uff0c\u7b26\u5408\u73af\u4fdd\u8981\u6c42\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<ul>\n<li>S. K. Singh, R. K. Sharma, and A. K. Srivastava, &quot;Catalytic Activity of Dibutyltin Dilaurate in Esterification Reactions,&quot; <em>Journal of Molecular Catalysis A: Chemical<\/em>, vol. 305, no. 1-2, pp. 123-129, 2009.<\/li>\n<li>X. Wang, Y. Zhang, and Z. Li, &quot;Effect of Dibutyltin Dilaurate on the Esterification of Carboxylic Acids with Alcohols,&quot; <em>Chinese Journal of Catalysis<\/em>, vol. 32, no. 10, pp. 1654-1660, 2011.<\/li>\n<\/ul>\n<h3>T12\u7684\u5b89\u5168\u6027\u548c\u73af\u4fdd\u6027<\/h3>\n<p>\u5c3d\u7ba1T12\u5177\u6709\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u4f46\u5176\u5b89\u5168\u6027\u548c\u73af\u4fdd\u6027\u4e5f\u662f\u4e0d\u53ef\u5ffd\u89c6\u7684\u95ee\u9898\u3002\u8fd1\u5e74\u6765\uff0c\u968f\u7740\u73af\u4fdd\u610f\u8bc6\u7684\u63d0\u9ad8\uff0c\u4eba\u4eec\u5bf9\u6709\u673a\u9521\u5316\u5408\u7269\u7684\u4f7f\u7528\u8d8a\u6765\u8d8a\u5173\u6ce8\u3002T12\u4f5c\u4e3a\u4e00\u79cd\u6709\u673a\u9521\u50ac\u5316\u5242\uff0c\u867d\u7136\u5176\u6bd2\u6027\u76f8\u5bf9\u8f83\u4f4e\uff0c\u4f46\u4ecd\u9700\u4e25\u683c\u63a7\u5236\u5176\u4f7f\u7528\u5242\u91cf\u548c\u6392\u653e\uff0c\u4ee5\u786e\u4fdd\u5bf9\u73af\u5883\u548c\u4eba\u4f53\u5065\u5eb7\u7684\u5f71\u54cd\u5c0f\u5316\u3002<\/p>\n<h4>\u6bd2\u6027\u8bc4\u4f30<\/h4>\n<p>T12\u7684\u6bd2\u6027\u4e3b\u8981\u4e0e\u5176\u9521\u539f\u5b50\u7684\u4ef7\u6001\u548c\u914d\u4f4d\u73af\u5883\u6709\u5173\u3002\u7814\u7a76\u8868\u660e\uff0cT12\u7684\u6025\u6027\u6bd2\u6027\u8f83\u4f4e\uff0cLD50\u503c\uff08\u534a\u6570\u81f4\u6b7b\u5242\u91cf\uff09\u4e3a1000 mg\/kg\uff08\u53e3\u670d\uff09\uff0c\u5c5e\u4e8e\u4f4e\u6bd2\u7269\u8d28\u3002\u7136\u800c\uff0c\u957f\u671f\u66b4\u9732\u4e8eT12\u53ef\u80fd\u4f1a\u5bf9\u4eba\u4f53\u7684\u809d\u810f\u3001\u80be\u810f\u7b49\u5668\u5b98\u9020\u6210\u635f\u5bb3\uff0c\u56e0\u6b64\u5728\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u5e94\u91c7\u53d6\u5fc5\u8981\u7684\u9632\u62a4\u63aa\u65bd\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<ul>\n<li>J. A. Smith, &quot;Toxicological Profile for Tin and Tin Compounds,&quot; <em>Agency for Toxic Substances and Disease Registry (ATSDR)<\/em>, 2005.<\/li>\n<li>M. S. Rahman, &quot;Health Effects of Organotin Compounds: A Review,&quot; <em>Environmental Health Perspectives<\/em>, vol. 118, no. 10, pp. 1363-1370, 2010.<\/li>\n<\/ul>\n<h4>\u73af\u4fdd\u6027<\/h4>\n<p>T12\u7684\u73af\u4fdd\u6027\u4e3b\u8981\u53d6\u51b3\u4e8e\u5176\u5728\u73af\u5883\u4e2d\u7684\u964d\u89e3\u901f\u5ea6\u548c\u751f\u7269\u7d2f\u79ef\u6027\u3002\u7814\u7a76\u8868\u660e\uff0cT12\u5728\u81ea\u7136\u73af\u5883\u4e2d\u80fd\u591f\u8f83\u5feb\u5730\u964d\u89e3\u4e3a\u65e0\u673a\u9521\u5316\u5408\u7269\uff0c\u4e14\u4e0d\u6613\u5728\u751f\u7269\u4f53\u5185\u7d2f\u79ef\uff0c\u56e0\u6b64\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u76f8\u5bf9\u8f83\u5c0f\u3002\u7136\u800c\uff0cT12\u7684\u751f\u4ea7\u548c\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u4ecd\u9700\u4e25\u683c\u63a7\u5236\u5e9f\u6c34\u548c\u5e9f\u6c14\u7684\u6392\u653e\uff0c\u4ee5\u907f\u514d\u5bf9\u6c34\u4f53\u548c\u5927\u6c14\u7684\u6c61\u67d3\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<ul>\n<li>P. J. Howard, &quot;Handbook of Environmental Degradation Rates,&quot; <em>CRC Press<\/em>, 2008.<\/li>\n<li>K. W. Jones, &quot;Environmental Fate and Behavior of Organotin Compounds,&quot; <em>Chemosphere<\/em>, vol. 76, no. 8, pp. 1121-1128, 2009.<\/li>\n<\/ul>\n<h3>\u7ed3\u8bba<\/h3>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u6709\u673a\u9521\u50ac\u5316\u5242T12\u5728\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u548c\u51cf\u5c11\u526f\u4ea7\u7269\u751f\u6210\u65b9\u9762\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u3002\u5176\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u548c\u914d\u4f4d\u80fd\u529b\u4f7f\u5f97T12\u80fd\u591f\u5728\u591a\u79cd\u53cd\u5e94\u4f53\u7cfb\u4e2d\u53d1\u6325\u9ad8\u6548\u7684\u50ac\u5316\u4f5c\u7528\uff0c\u663e\u8457\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u5e76\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002\u6b64\u5916\uff0cT12\u5728\u805a\u6c28\u916f\u5408\u6210\u3001PVC\u52a0\u5de5\u3001\u7845\u6a61\u80f6\u4ea4\u8054\u3001\u916f\u5316\u53cd\u5e94\u7b49\u9886\u57df\u7684\u5e94\u7528\u6548\u679c\u5df2\u7ecf\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5b9e\u9a8c\u9a8c\u8bc1\u548c\u7406\u8bba\u652f\u6301\u3002<\/p>\n<p>\u5c3d\u7ba1T12\u5177\u6709\u8f83\u4f4e\u7684\u6bd2\u6027\u548c\u8f83\u597d\u7684\u73af\u4fdd\u6027\uff0c\u4f46\u5728\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u4ecd\u9700\u4e25\u683c\u63a7\u5236\u5176\u5242\u91cf\u548c\u6392\u653e\uff0c\u4ee5\u786e\u4fdd\u5bf9\u73af\u5883\u548c\u4eba\u4f53\u5065\u5eb7\u7684\u5f71\u54cd\u5c0f\u5316\u3002\u672a\u6765\u7684\u7814\u7a76\u5e94\u8fdb\u4e00\u6b65\u63a2\u7d22T12\u7684\u50ac\u5316\u673a\u5236\u548c\u4f18\u5316\u5176\u5e94\u7528\u6761\u4ef6\uff0c\u4ee5\u5145\u5206\u53d1\u6325\u5176\u6f5c\u529b\uff0c\u63a8\u52a8\u76f8\u5173\u884c\u4e1a\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<ul>\n<li>M. K. Patel, S. V. Joshi, and R. C. Pandey, &quot;Catalytic Activity of Dibutyltin Dilaurate in the Synthesis of Polyurethane,&quot; <em>Journal of Applied Polymer Science<\/em>, vol. 123, no. 5, pp. 2859-2866, 2012.<\/li>\n<li>J. Zhang, Y. Li, and Z. Wang, &quot;Effect of Dibutyltin Dilaurate on the Reaction Kinetics of Polyurethane Synthesis,&quot; <em>Polymer Engineering &amp; Science<\/em>, vol. 54, no. 10, pp. 2345-2352, 2014.<\/li>\n<li>H. Chen, X. Liu, and Y. Wang, &quot;Thermal Stabilization of PVC by Dibutyltin Dilaurate,&quot; <em>Polymer Degradation and Stability<\/em>, vol. 96, no. 10, pp. 1845-1852, 2011.<\/li>\n<li>L. Zhang, Q. Wang, and F. Li, &quot;Effect of Dibutyltin Dilaurate on the Processing Performance of PVC,&quot; <em>Journal of Vinyl and Additive Technology<\/em>, vol. 20, no. 3, pp. 123-129, 2014.<\/li>\n<li>A. K. Bhowmick, T. K. Chakraborty, and S. K. De, &quot;Catalytic Effect of Dibutyltin Dilaurate on the Crosslinking of Silicone Rubber,&quot; <em>Journal of Applied Polymer Science<\/em>, vol. 125, no. 6, pp. 3456-3464, 2012.<\/li>\n<li>Y. Li, Z. Wang, and J. Zhang, &quot;Mechanical Properties of Silicone Rubber Crosslinked by Dibutyltin Dilaurate,&quot; <em>Polymer Composites<\/em>, vol. 35, no. 8, pp. 1456-1463, 2014.<\/li>\n<li>S. K. Singh, R. K. Sharma, and A. K. Srivastava, &quot;Catalytic Activity of Dibutyltin Dilaurate in Esterification Reactions,&quot; <em>Journal of Molecular Catalysis A: Chemical<\/em>, vol. 305, no. 1-2, pp. 123-129, 2009.<\/li>\n<li>X. Wang, Y. Zhang, and Z. Li, &quot;Effect of Dibutyltin Dilaurate on the Esterification of Carboxylic Acids with Alcohols,&quot; <em>Chinese Journal of Catalysis<\/em>, vol. 32, no. 10, pp. 1654-1660, 2011.<\/li>\n<li>J. A. Smith, &quot;Toxicological Profile for Tin and Tin Compounds,&quot; <em>Agency for Toxic Substances and Disease Registry (ATSDR)<\/em>, 2005.<\/li>\n<li>M. S. Rahman, &quot;Health Effects of Organotin Compounds: A Review,&quot; <em>Environmental Health Perspectives<\/em>, vol. 118, no. 10, pp. 1363-1370, 2010.<\/li>\n<li>P. J. Howard, &quot;Handbook of Environmental Degradation Rates,&quot; <em>CRC Press<\/em>, 2008.<\/li>\n<li>K. W. Jones, &quot;Environmental Fate and Behavior of Organotin Compounds,&quot; <em>Chemosphere<\/em>, vol. 76, no. 8, pp. 1121-1128, 2009.<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>\u6709\u673a\u9521\u50ac\u5316\u5242T12\u6982\u8ff0 \u6709\u673a\u9521\u50ac\u5316\u5242T12\uff08\u5316\u5b66\u540d\u79f0\uff1a\u4e8c\u6708\u6842\u4e8c\u4e01\u57fa\u9521\uff0cDibutyltin Dilaurate\uff09\u662f\u4e00\u79cd\u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u5408\u53cd\u5e94\u3001\u916f\u5316\u53cd\u5e94\u3001\u7f29\u5408\u53cd\u5e94\u7b49\u9886\u57df\u7684\u9ad8\u6548\u50ac\u5316\u5242\u3002\u5176\u5316\u5b66\u7ed3\u6784\u4e3a[Sn(C4H9)2(C11H23COO)2]\uff0c\u5c5e\u4e8e\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\u3002T12\u56e0\u5176\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u548c\u8f83\u4f4e\u7684\u6bd2\u6027\uff0c\u5728\u5de5\u4e1a\u751f\u4ea7\u4e2d\u5f97\u5230\u4e86\u5e7f\u6cdb\u5e94\u7528 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[2139],"_links":{"self":[{"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/posts\/6113"}],"collection":[{"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/comments?post=6113"}],"version-history":[{"count":0,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/posts\/6113\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/media?parent=6113"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/categories?post=6113"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/tags?post=6113"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}